(3-diphenylphosphanyl)-2-thionaphthol | 1161924-37-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-diphenylphosphanyl)-2-thionaphthol
• 英文别名: 3-Diphenylphosphanylnaphthalene-2-thiol；3-diphenylphosphanylnaphthalene-2-thiol
• CAS: 1161924-37-3
• 化学式: C₂₂H₁₇PS
• 分子量: 344.417
• InChiKey: HODFRZQAYHPVEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (3-diphenylphosphanyl)-2-thionaphthol 以 四氢呋喃 为溶剂， 生成 (2-diphenylphosphanyl)-2-thionaphtholato[P,S]bis(trimethylphosphine)nickel
  参考文献：
  名称：

  Syntheses and properties of molecular nickel(II) hydride, methyl, and nickel(I) complexes supported by trimethylphosphane and (2-diphenylphosphanyl)thiophenolato and -naphtholato ligands

  摘要：

  2-Diphenylphosphanyl) thiophenol (PpSH) or (3-diphenylphosphanyl)-2-thionaphthol (PnSH) react with Ni(PMe3)(4) to form NiH(PpS)(PMe3)(2) (1) or NiH(PnS)(PMe3)(2) (2). 1,3-Bis(diphenylphosphanyl) propane (PP) replaces the monodentate phosphane ligands to give NiH(PpS)(PP) (3). NiMe(OMe)(PMe3) or NiMe2(PMe3)(3) react with PpSH to form NiMe(PpS)(PM3) (4) and NiMe( PpS)( PMe3)(2) (5), respectively, and PnSH affords NiMe(PnS)(PMe3)(2) (6), NiMe(PnS)(PMe3) (7). Dissociation of PMe3 ligands induces transformation of 1 to Ni(PpS)(PMe3)(2) (8) and Ni(PpS)(2). Crystal and molecular structures are given for 1, 5- 8, and dynamic solution spectra (NMR, EPR) are discussed. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.01.023
• 作为产物：
  描述：

  二苯基氯化膦 、 2-萘硫醇 在 正丁基锂 、 四甲基乙二胺 作用下， 以 环己烷 为溶剂， 反应 16.0h， 以21%的产率得到(3-diphenylphosphanyl)-2-thionaphthol
  参考文献：
  名称：

  Syntheses and properties of molecular nickel(II) hydride, methyl, and nickel(I) complexes supported by trimethylphosphane and (2-diphenylphosphanyl)thiophenolato and -naphtholato ligands

  摘要：

  2-Diphenylphosphanyl) thiophenol (PpSH) or (3-diphenylphosphanyl)-2-thionaphthol (PnSH) react with Ni(PMe3)(4) to form NiH(PpS)(PMe3)(2) (1) or NiH(PnS)(PMe3)(2) (2). 1,3-Bis(diphenylphosphanyl) propane (PP) replaces the monodentate phosphane ligands to give NiH(PpS)(PP) (3). NiMe(OMe)(PMe3) or NiMe2(PMe3)(3) react with PpSH to form NiMe(PpS)(PM3) (4) and NiMe( PpS)( PMe3)(2) (5), respectively, and PnSH affords NiMe(PnS)(PMe3)(2) (6), NiMe(PnS)(PMe3) (7). Dissociation of PMe3 ligands induces transformation of 1 to Ni(PpS)(PMe3)(2) (8) and Ni(PpS)(2). Crystal and molecular structures are given for 1, 5- 8, and dynamic solution spectra (NMR, EPR) are discussed. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.01.023

文献信息

• Syntheses and properties of molecular nickel(II) hydride, methyl, and nickel(I) complexes supported by trimethylphosphane and (2-diphenylphosphanyl)thiophenolato and -naphtholato ligands
  作者：Peter B. Kraikivskii、Markus Frey、Hamdi A. Bennour、Armin Gembus、Ralf Hauptmann、Ingrid Svoboda、Hartmut Fuess、Vitaly V. Saraev、Hans-Friedrich Klein

  DOI：10.1016/j.jorganchem.2009.01.023

  日期：2009.5

  2-Diphenylphosphanyl) thiophenol (PpSH) or (3-diphenylphosphanyl)-2-thionaphthol (PnSH) react with Ni(PMe3)(4) to form NiH(PpS)(PMe3)(2) (1) or NiH(PnS)(PMe3)(2) (2). 1,3-Bis(diphenylphosphanyl) propane (PP) replaces the monodentate phosphane ligands to give NiH(PpS)(PP) (3). NiMe(OMe)(PMe3) or NiMe2(PMe3)(3) react with PpSH to form NiMe(PpS)(PM3) (4) and NiMe( PpS)( PMe3)(2) (5), respectively, and PnSH affords NiMe(PnS)(PMe3)(2) (6), NiMe(PnS)(PMe3) (7). Dissociation of PMe3 ligands induces transformation of 1 to Ni(PpS)(PMe3)(2) (8) and Ni(PpS)(2). Crystal and molecular structures are given for 1, 5- 8, and dynamic solution spectra (NMR, EPR) are discussed. (C) 2009 Elsevier B.V. All rights reserved.