N,N-diallylmorpholiniumchloride | 13239-81-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: N,N-diallylmorpholiniumchloride
• 英文别名: 4,4-diallyl-morpholinium; chloride；N,N-diallylmorpholinium chloride；4,4-bis(prop-2-enyl)morpholin-4-ium;chloride
• CAS: 13239-81-1
• 化学式: C₁₀H₁₈NO*Cl
• 分子量: 203.712
• InChiKey: WLJRDEQZJUDWKH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.79
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 N,N-diallylmorpholiniumchloride 以 乙醇 为溶剂， 生成 [N,N'-diallylmorpholinium][Cu4Cl5]
  参考文献：
  名称：

  摘要：

  The compounds [C4H8ON(C3H5)(2)(+)[Cu4Cl5](-) (I), [C4H8ONH(C3H5)](+)[CuBr2](-) (II), and [C4H8ONH(C3H5)](+)[CuBr1.41]Cl-0.59](-) (III) were prepared for the first time by ac electrochemical synthesis from mono- and di-N-allyl derivatives of morpholinium and copper(I) halides in ethanol solution and structurally characterized. In the structure of I pi-complex, the centrosymmetric Cu8Cl10 fragments are associated into layers perpendicular to the b axis. The N,N'-diallylmorpholinium cation functions as a bridge, which coordinates two copper atom of the adjacent inorganic fragments by both allyl groups. The trigonal-pyramidal surrounding of the Cu(I) atom, as well as the distorted tetrahedral coordination sphere of Cu(2), involves three chlorine atoms and the C=C bond, whereas the planar trigonal surrounding of the Cu(3) atom and trigonal-pyramidal surrounding of the Cu(4) atom involve only chlorine atoms. In the isostructural II and III sigma-complexes, the edge-shared CuX4 tetrahedra form the infinite copper-halide chains running along the a axis. The inorganic fragments and organic N-allylmorpholinium cations are united into the three-dimensional crystal structures by N-H (...) X and C-H (...) X (X = Cl, Br) hydrogen bonds.

  DOI：

  10.1023/a:1024787231747
• 作为产物：
  描述：

  4-烯丙基吗啉 、 3-氯丙烯 在 potassium iodide 作用下， 反应 360.5h， 生成 N,N-diallylmorpholiniumchloride
  参考文献：
  名称：

  SYNTHESIS OF PURE DIALLYL MORPHOLINIUM MONOMERS IN HIGH YIELDS AND USING ANTIBACTERIAL EFFECT OF THEIR SPIRO POLYMERS

  摘要：

  本文介绍了合成N,N-二烯丙基吗啡铵单体并聚合成高产率和高纯度环的方法。该过程涉及合成N,N-二烯丙基吗啡铵溴化物和氯化物，然后部分或完全用硼酸盐、对甲苯磺酸盐、油酸盐和乙酸盐的阴离子交换。单体的环聚合生成水溶性聚合物，每个重复单元中带有季铵盐基团，其水溶液作为杀菌溶液具有优势，适用于制备家用抗菌配方。具有溴化物和硼酸盐阴离子的聚合物是一种有效的抗菌剂，能够杀死“铜绿假单胞菌”，这是最难应对的医院细菌，以及各种常见的细菌。这些配方适用于生产杀菌湿巾和形成无菌表面，当与空调器结合时，还能产生无菌空气。

  公开号：

  US20160286809A1

文献信息

• A heat-sealable thermoplastic film structure with antistatic properties
  申请人：MOBIL OIL CORPORATION

  公开号：EP0102209A2

  公开（公告）日：1984-03-07

  A multilayer film structure is inhibited against the accumulation of static charge on the surfaces thereof by the inclusion in a buried primer layer thereof of a linear high molecular weight water-soluble quaternary ammonium chloride polymer.

  在多层薄膜结构的埋底层中加入线性高分子量水溶性季铵氯化物聚合物，可抑制静电荷在其表面的积累。
• Process for the preparation of copolymers of monoallylamine and diallylamine derivatives
  申请人：NITTO BOSEKI CO., LTD.

  公开号：EP0140309A2

  公开（公告）日：1985-05-08

  A monoallylamine-diallylamine derivative copolymer with a high degree of polymerization can be obtained in a high yield by using a radical initiator containing an azo group and a group having cationic nitrogen atom in the molecule.

  使用含有偶氮基团和分子中含有阳离子氮原子的基团的自由基引发剂，可以高产率地获得聚合度高的单烯丙基胺-二烯丙基胺衍生物共聚物。
• Preparation and Polymerization of Unsaturated Quaternary Ammonium Compounds
  作者：George B. Butler、Robert L. Bunch

  DOI：10.1021/ja01177a053

  日期：1949.9
• US4812540A
  申请人：——

  公开号：US4812540A

  公开（公告）日：1989-03-14
• SYNTHESIS OF PURE DIALLYL MORPHOLINIUM MONOMERS IN HIGH YIELDS AND USING ANTIBACTERIAL EFFECT OF THEIR SPIRO POLYMERS
  申请人：BICAK Tugrul Cem

  公开号：US20160286809A1

  公开（公告）日：2016-10-06

  Herein, the synthesis of N,Ndiallyl morpholinium monomers and polymerization of the same to form rings at high yield and purity are explained. The process involves the synthesis of N,Ndiallyl morpholinium bromide and chloride and subsequently partially or completely exchanging their anions with borate, p-toluenesulfonate, oleate, and acetate anions. The cyclopolimerization of monomers yields water soluble polymers carrying quaternary ammonium groups in each repeated unit, whose aqueous solutions act as a bactericide solution. These solutions are advantageous in preparation of antibacterial formulations intended for domestic use. The polymer with bromide and borate anions is an efficient antibacterial which is able to kill “ Pseudomonas Aeruginosa ”, the hardest hospital bacterium to cope with, as well as various common bacteria. These formulations are suitable for producing bactericide wet wipes and forming abacterial surfaces and, when combined with air conditioners, generating bacteria free air.

  本文介绍了合成N,N-二烯丙基吗啡铵单体并聚合成高产率和高纯度环的方法。该过程涉及合成N,N-二烯丙基吗啡铵溴化物和氯化物，然后部分或完全用硼酸盐、对甲苯磺酸盐、油酸盐和乙酸盐的阴离子交换。单体的环聚合生成水溶性聚合物，每个重复单元中带有季铵盐基团，其水溶液作为杀菌溶液具有优势，适用于制备家用抗菌配方。具有溴化物和硼酸盐阴离子的聚合物是一种有效的抗菌剂，能够杀死“铜绿假单胞菌”，这是最难应对的医院细菌，以及各种常见的细菌。这些配方适用于生产杀菌湿巾和形成无菌表面，当与空调器结合时，还能产生无菌空气。