5-(5,8-Diamino-1,3-dioxobenzo[de]isoquinolin-2-yl)benzene-1,3-dicarboxylic acid | 1354701-68-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(5,8-Diamino-1,3-dioxobenzo[de]isoquinolin-2-yl)benzene-1,3-dicarboxylic acid
• 英文别名: 5-(5,8-diamino-1,3-dioxobenzo[de]isoquinolin-2-yl)benzene-1,3-dicarboxylic acid
• CAS: 1354701-68-0
• 化学式: C₂₀H₁₃N₃O₆
• 分子量: 391.34
• InChiKey: LXSZEARFGFVDCS-UHFFFAOYSA-N

物化性质

• 熔点：
  >300 °C
• 沸点：
  887.1±65.0 °C(Predicted)
• 密度：
  1.697±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  29
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  164
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  N-(3',5'-dicarboxyphenyl)-3,6-dinitro-1,8-naphthalimide 在 palladium 10% on activated carbon 、 氢气 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 25.0 ℃ 、100.0 kPa 条件下， 反应 16.0h， 生成 5-(5,8-Diamino-1,3-dioxobenzo[de]isoquinolin-2-yl)benzene-1,3-dicarboxylic acid
  参考文献：
  名称：

  The synthesis and fluorescence properties of macromolecular components based on 1,8-naphthalimide derivatives and dimers

  摘要：

  A series of novel 1,8-naphthalimide derivatives and dimers possessing reactive carboxylic acid, nitro, amine, or bromide functionality is prepared and their photophysical properties are studied. Those derivatives that contain amine substituents attached directly to the 1,8-naphthalimide unit display intense yellow-green fluorescence. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.12.009

文献信息

• The synthesis and fluorescence properties of macromolecular components based on 1,8-naphthalimide derivatives and dimers
  作者：Alaa M.M. El-Betany、Neil B. McKeown

  DOI：10.1016/j.tetlet.2011.12.009

  日期：2012.2

  A series of novel 1,8-naphthalimide derivatives and dimers possessing reactive carboxylic acid, nitro, amine, or bromide functionality is prepared and their photophysical properties are studied. Those derivatives that contain amine substituents attached directly to the 1,8-naphthalimide unit display intense yellow-green fluorescence. (C) 2011 Elsevier Ltd. All rights reserved.