1,2-bis(di(pentafluorophenyl)phosphino)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(di(pentafluorophenyl)phosphino)benzene
• 英文别名: [2-Bis(2,3,4,5,6-pentafluorophenyl)phosphanylphenyl]-bis(2,3,4,5,6-pentafluorophenyl)phosphane；[2-bis(2,3,4,5,6-pentafluorophenyl)phosphanylphenyl]-bis(2,3,4,5,6-pentafluorophenyl)phosphane
• 化学式: C₃₀H₄F₂₀P₂
• 分子量: 806.277
• InChiKey: FZSLFUFPGLGHHE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  52
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  20

反应信息

• 作为反应物：
  描述：

  水合三氯化钌 、 1-(4-phenylamino)-1-(phenylhydrazono)propan-2-one 、 1,2-bis(di(pentafluorophenyl)phosphino)benzene 以 乙醇 为溶剂， 以20%的产率得到cis-Cl2Ru(PhN=NC(COCH3)=NPh)(1,2-bis(di(pentafluorophenyl)phosphino)benzene)
  参考文献：
  名称：

  cis–trans Isomerism in mixed-ligand ruthenium(II) complexes containing bis(phosphine) and azoimine ligands

  摘要：

  This study presents the syntheses and characterization of mixed-ligand azoimine-diphosphine ruthenium complexes of the general formula [RuCl2(Azo)(P-P)] (C1-C5) (Azo = C6H5N=NC(COCH3)=NC6H5; P-P = 1,2-bis(dimethylphosphino)ethane (dmpe) (C1), cis-1,2-bis(diphenylphosphino)ethylene (depe) (C2), 1.1'-bis(diphenylphosphino)methane (dppm) (C3), 1,2-bis(diphenylphosphino)benzene (dbpe) (C4),1, 2-bis(di(pentaflurophenyl)phosphino)ethane (F-dppe) (C5)). These complexes were synthesized via the reaction of RuCl3, azoimine and the diphosphine ligands in ethanol solutions. The X-ray structure of C2 reveals a cis-dichloro geometry, in spite of the bulky P-P ligand, and this is attributed to the presence of an intramolecular pi-pi interaction between benzene rings (on the Azo and P-P ligands) [centroid-centroid distances = 3.596 and 3.654 angstrom; dihedral angle between ring planes = 13.2(3) and 15.4(4)degrees for the two independent molecules]. In contrast, the X-ray structure of C1, with a less bulky dmpe ligand in which no Ph rings are available for pi-pi bonding, revealed a trans-dichloro geometry. In addition to the X-ray structures of Cl and C2, this work presents and discusses the spectroscopic (IR, UV-Vis, H-1 NMR and P-31 NMR) and electrochemical (cyclic voltammetry) behavior of C1-C5. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.04.044

文献信息

• COMPOSITION AND POLYMER
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP2735581B1

  公开（公告）日：2021-07-14
• Composition and Polymer
  申请人：Nakamura Akitake

  公开号：US20140121293A1

  公开（公告）日：2014-05-01

  Disclosed is a composition comprising (A) at least one compound selected from the group consisting of an ether compound having two or more ether groups, a trivalent phosphorus compound, and a ketone compound, (B) a boron trihalide, and (C) an episulfide compound.
• US9334371B2
  申请人：——

  公开号：US9334371B2

  公开（公告）日：2016-05-10
• US9738757B2
  申请人：——

  公开号：US9738757B2

  公开（公告）日：2017-08-22
• cis–trans Isomerism in mixed-ligand ruthenium(II) complexes containing bis(phosphine) and azoimine ligands
  作者：Mousa Al-Noaimi、Mahmoud Sunjuk、Mohammad El-khateeb、Salim F. Haddad、Alaa Haniyeh、Murad AlDamen

  DOI：10.1016/j.poly.2012.04.044

  日期：2012.7

  This study presents the syntheses and characterization of mixed-ligand azoimine-diphosphine ruthenium complexes of the general formula [RuCl2(Azo)(P-P)] (C1-C5) (Azo = C6H5N=NC(COCH3)=NC6H5; P-P = 1,2-bis(dimethylphosphino)ethane (dmpe) (C1), cis-1,2-bis(diphenylphosphino)ethylene (depe) (C2), 1.1'-bis(diphenylphosphino)methane (dppm) (C3), 1,2-bis(diphenylphosphino)benzene (dbpe) (C4),1, 2-bis(di(pentaflurophenyl)phosphino)ethane (F-dppe) (C5)). These complexes were synthesized via the reaction of RuCl3, azoimine and the diphosphine ligands in ethanol solutions. The X-ray structure of C2 reveals a cis-dichloro geometry, in spite of the bulky P-P ligand, and this is attributed to the presence of an intramolecular pi-pi interaction between benzene rings (on the Azo and P-P ligands) [centroid-centroid distances = 3.596 and 3.654 angstrom; dihedral angle between ring planes = 13.2(3) and 15.4(4)degrees for the two independent molecules]. In contrast, the X-ray structure of C1, with a less bulky dmpe ligand in which no Ph rings are available for pi-pi bonding, revealed a trans-dichloro geometry. In addition to the X-ray structures of Cl and C2, this work presents and discusses the spectroscopic (IR, UV-Vis, H-1 NMR and P-31 NMR) and electrochemical (cyclic voltammetry) behavior of C1-C5. (c) 2012 Elsevier Ltd. All rights reserved.