P-Benzyl-N,N,N',N'-tetraethylphosphonous diamide | 93633-48-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: P-Benzyl-N,N,N',N'-tetraethylphosphonous diamide
• 英文别名: N-[benzyl(diethylamino)phosphanyl]-N-ethylethanamine
• CAS: 93633-48-8
• 化学式: C₁₅H₂₇N₂P
• 分子量: 266.367
• InChiKey: JQMRXNYWMPPFKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  P-Benzyl-N,N,N',N'-tetraethylphosphonous diamide 在 1,2,3,4,5,6,7,8-八硫杂环辛烷 作用下， 以 甲苯 为溶剂， 反应 1.0h， 以0.15 g的产率得到P-benzyl-N,N,N',N'-tetraethylphosphonothioic diamide
  参考文献：
  名称：

  An Unconventional Synthesis of Dibromophosphines

  摘要：

  Dibromophosphines, RPBr2, are obtained by reaction of tetrabromomethane with 7-substituted 7-phosphanorbornenes in toluene at ca. 100 degrees C. The phosphanorbornenes are obtained in situ by cycloaddition of N-phenylmaleimide with 1-substituted 3,4-di-methylphospholes. The overall reaction sequence shows a good compatibility with functional groups.

  DOI：

  10.1055/s-0033-1339548
• 作为产物：
  描述：

  在 四溴化碳 作用下， 以 甲苯 为溶剂， 反应 0.67h， 生成 P-Benzyl-N,N,N',N'-tetraethylphosphonous diamide
  参考文献：
  名称：

  An Unconventional Synthesis of Dibromophosphines

  摘要：

  Dibromophosphines, RPBr2, are obtained by reaction of tetrabromomethane with 7-substituted 7-phosphanorbornenes in toluene at ca. 100 degrees C. The phosphanorbornenes are obtained in situ by cycloaddition of N-phenylmaleimide with 1-substituted 3,4-di-methylphospholes. The overall reaction sequence shows a good compatibility with functional groups.

  DOI：

  10.1055/s-0033-1339548

文献信息

• SVARA, J.;FLUCK, E., SYNTH. AND REACT. INORG. AND METAL-ORG. CHEM., 1984, 14, N 6, 869-879
  作者：SVARA, J.、FLUCK, E.

  DOI：——

  日期：——
• An Unconventional Synthesis of Dibromophosphines
  作者：Zheng Duan、François Mathey、Lili Wang、Lujun Zhang、Hanyu Shi

  DOI：10.1055/s-0033-1339548

  日期：——

  Dibromophosphines, RPBr2, are obtained by reaction of tetrabromomethane with 7-substituted 7-phosphanorbornenes in toluene at ca. 100 degrees C. The phosphanorbornenes are obtained in situ by cycloaddition of N-phenylmaleimide with 1-substituted 3,4-di-methylphospholes. The overall reaction sequence shows a good compatibility with functional groups.