2,2':5',2'-Terpyrrol | 3260-45-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 2,2':5',2'-Terpyrrol
• 英文别名: 2,5-bis(1H-pyrrol-2-yl)-1H-pyrrole
• CAS: 3260-45-5
• 化学式: C₁₂H₁₁N₃
• 分子量: 197.239
• InChiKey: ZQZGBCKEODHDGQ-UHFFFAOYSA-N

物化性质

• 熔点：
  241-242 °C
• 沸点：
  531.8±40.0 °C(Predicted)
• 密度：
  1.272±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.4
• 氢给体数：
  3
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-甲基磺酰基吡咯-2-羧醛 在 3-苄基羟乙基甲基噻唑氯化锂 sodium hydroxide 、 ammonium acetate 、 sodium acetate 、 乙酸酐 作用下， 以 甲醇 、 乙醇 、 丙酸 为溶剂， 生成 2,2':5',2'-Terpyrrol
  参考文献：
  名称：

  A general synthetic route to 2,2':5',2''-terpyrrole, 2,5-di(2-pyrryl)thiophene, and alkyl-substituted analogs

  摘要：

  DOI：

  10.1021/jo00296a062

文献信息

• PROCESSES FOR PREPARING CURED FILMS, THE RESULTING FILMS, AND PLASMA-INITIATED POLYMERIZABLE COMPOSITIONS
  申请人：FUJIFILM Corporation

  公开号：US20140170405A1

  公开（公告）日：2014-06-19

  Provided are novel plasma-assisted processes for preparing cured films having excellent heat resistance and moisture resistance. A process for preparing a cured film, comprising at least: applying a composition containing (A) at least one conductive polymer precursor on a substrate to form a coating layer, and irradiating the coating layer with a plasma to polymerize the conductive polymer precursor (A).

  提供了一种新型等离子体辅助制备固化膜的工艺，该固化膜具有优异的耐热性和耐潮性。一种制备固化膜的工艺，包括至少以下步骤：在基板上涂布含有（A）至少一种导电聚合物前体的组合物以形成涂层层，然后用等离子体照射涂层层以聚合导电聚合物前体（A）。
• Photoacid Generators And Lithographic Resists Comprising The Same
  申请人：University Of North Carolina At Charlotte

  公开号：US20140315130A1

  公开（公告）日：2014-10-23

  The present invention provides photoacid generators for use in chemically amplified resists and lithographic processes using the same.

  本发明提供了用于化学增强型光刻胶和使用其的光刻工艺的光酸发生剂。
• CHARGE-TRANSPORTING ORGANIC MATERIAL CONTAINING COMPOUND HAVING 1,4-DITHIIN RING
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP1691586A1

  公开（公告）日：2006-08-16

  A charge-transporting organic material containing a compound with a 1,4-dithiin ring, which is represented by the following formula (1), is described. When using a thin film made of such an organic material in a low-molecular-weight organic EL (OLED) element and a polymer organic EL (PLED) element, EL element characteristics such as low drive voltage and high luminous efficiency can be improved. In addition, a charge-transporting varnish containing the compound with a 1,4-dithiin ring represented by the above formula (1) has good processing properties, and a thin film obtained therefrom has high charge-transporting characteristics and thus is effective for application to protective films for capacitor electrodes, antistatic films, solar cells or fuel cells.

  本文描述了一种电荷传输有机材料，它含有一个 1,4-二硫杂环化合物，由下式（1）表示。 在低分子量有机电致发光（OLED）元件和聚合物有机电致发光（PLED）元件中使用由这种有机材料制成的薄膜时，可以提高电致发光元件的特性，例如低驱动电压和高发光效率。此外，含有由上式（1）表示的具有 1，4-二硫环的化合物的电荷传输清漆具有良好的加工性能，由此获得的薄膜具有高电荷传输特性，因此可有效地应用于电容器电极保护膜、抗静电膜、太阳能电池或燃料电池。
• MERRILL, BRYON A.;LEGOFF, EUGENE, J. ORG. CHEM., 55,(1990) N, C. 2904-2908
  作者：MERRILL, BRYON A.、LEGOFF, EUGENE

  DOI：——

  日期：——
• Charge-transporting organic material containing compound having 1,4-dithiin ring
  申请人：Yoshimoto Takuji

  公开号：US20070043222A1

  公开（公告）日：2007-02-22

  A charge-transporting organic material containing a compound with a 1,4-dithiin ring, which is represented by the following formula (1), is described. When using a thin film made of such an organic material in a low-molecular-weight organic EL (OLED) element and a polymer organic EL (PLED) element, EL element characteristics such as low drive voltage and high luminous efficiency can be improved. In addition, a charge-transporting varnish containing the compound with a 1,4-dithiin ring represented by the above formula (1) has good processing properties, and a thin film obtained therefrom has high charge-transporting characteristics and thus is effective for application to protective films for capacitor electrodes, antistatic films, solar cells or fuel cells.