4-Methylbenzoesaeure-methoxymethylester | 98386-20-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-Methylbenzoesaeure-methoxymethylester
• 英文别名: methoxymethyl 4-methylbenzoate
• CAS: 98386-20-0
• 化学式: C₁₀H₁₂O₃
• 分子量: 180.203
• InChiKey: VLLWGNPLRKFSMM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-Methylbenzoesaeure-methoxymethylester 、 苯 在 dipotassium peroxodisulfate 、 silver nitrate 作用下， 以 乙腈 为溶剂， 反应 20.0h， 以70%的产率得到methoxymethyl biphenyl-4-carboxylate
  参考文献：
  名称：

  两电子Ag（I）/ Ag（III）催化剂过度氧化可实现不带预功能化的直接芳基-芳基偶联

  摘要：

  本文报道的是通过串联催化策略通过惰性C sp 2 -CH 3和C sp 2 -H之间的偶联形成不对称联芳基的催化平台。该平台利用传统的AgNO 3催化剂和过量的K 2 S 2 O 8氧化剂。过量的氧化剂将传统的单电子Ag（I）/ Ag（II）化学转化为两电子Ag（I）/ Ag（III），从而可以通过使用未活化的廉价商品一锅合成芳基-芳基支架化学药品。

  DOI：

  10.1002/adsc.201800213
• 作为产物：
  描述：

  sodium p-methylbenzoate 、 氯甲基甲基醚 以 六甲基磷酰三胺 为溶剂， 反应 4.0h， 以63%的产率得到4-Methylbenzoesaeure-methoxymethylester
  参考文献：
  名称：

  Thomas, H. Guenter; Kessel, Stephan, Chemische Berichte, 1985, vol. 118, # 7, p. 2777 - 2788

  摘要：

  DOI：

文献信息

• HALOALKYLSULFONANILIDE DERIVATIVE
  申请人：Kai Masanori

  公开号：US20120029187A1

  公开（公告）日：2012-02-02

  Novel herbicides are provided. A haloalkylsulfonanilide derivative represented by the formula (1) or an agrochemically acceptable salt thereof: the formula (1): wherein Z is —C(R 9 )(R 10 )— or —N(R 11 )—, A is an oxygen atom, a sulfur atom or —N(R 12 )—, W is an oxygen atom or a sulfur atom, m is an integer of from 0 to 3, n is an integer of from 0 to 3, m+n is from 1 to 3, R 1 is halo C 1 -C 6 alkyl, R 2 is a hydrogen atom, C 1 -C 6 alkyl or the like, each of R 3 and R 4 is independently a hydrogen atom, C 1 -C 6 alkyl or the like, each of R 5 , R 6 , R 7 , R 8 , R 9 and R 10 is independently a hydrogen atom, a halogen, C 1 -C 6 alkyl or the like, each of R 11 and R 12 is a hydrogen atom, C 1 -C 6 alkyl, halo C 1 -C 6 alkyl or the like, and X is independently a hydrogen atom, a halogen, C 1 -C 6 alkyl, or the like.

  提供新型除草剂。 一种由式（1）表示的卤烷基磺酰苯胺衍生物或其农药可接受的盐： 式（1）： 其中Z为—C(R9)(R10)—或—N(R11)—，A为氧原子、硫原子或—N(R12)—，W为氧原子或硫原子，m为0至3的整数，n为0至3的整数，m+n为1至3，R1为卤代C1-C6烷基，R2为氢原子、C1-C6烷基或类似物，R3和R4中的每一个独立地为氢原子、C1-C6烷基或类似物，R5、R6、R7、R8、R9和R10中的每一个独立地为氢原子、卤素、C1-C6烷基或类似物，R11和R12中的每一个为氢原子、C1-C6烷基、卤代C1-C6烷基或类似物，X独立地为氢原子、卤素、C1-C6烷基或类似物。
• Mild deprotection of methoxymethyl, methylthiomethyl, methoxyethoxymethyl, and and β-(trimethylsilyl,)ethoxymethyl, esters with magnesium bromide in ether
  作者：Sunggak Kim、Young Hee Park、In Seo Kee

  DOI：10.1016/0040-4039(91)80699-7

  日期：1991.6

  MOM, MTM, MEM, and SEM esters are cleanly deprotected under mild conditions by treatment with magnesium bromide in ether at room temperature.

  MOM，MTM，MEM和SEM酯在温和条件下通过在室温下用溴化镁在乙醚中的处理干净地脱保护。
• ORTHO-SUBSTITUTED HALOALKYLSULFONANILIDE DERIVATIVE AND HERBICIDE
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP2336104A1

  公开（公告）日：2011-06-22

  Novel herbicides are provided. A haloalkylsulfonanilide derivative represented by the formula (1) or an agrochemically acceptable salt thereof: the formula (1): wherein A is -C(R7)(R8)- or -N(R9)-, W is an oxygen atom or a sulfur atom, n is an integer of from 1 to 4, R1 is halo C1 -C6 alkyl, R2 is a hydrogen atom, C1 - C6 alkyl or the like, each of R3 and R4 is independently a hydrogen atom, C1 - C6 alkyl or the like, each of R5, R6, R7 and R8 is independently a hydrogen atom, a halogen, C1 - C6 alkyl or the like, R9 is a hydrogen atom, C1 - C6 alkyl or the like, and X is halogen, C1 - C6 alkyl or the like.

  提供了新型除草剂。 由式（1）代表的卤代烷基磺酰苯胺衍生物或其农用化学品可接受的盐： 式 (1)： 其中A是-C(R7)(R8)-或-N(R9)-、 W 是氧原子或硫原子，n 是 1 至 4 的整数，R1 是卤代 C1 -C6 烷基，R2 是氢原子、C1 -C6 烷基或类似物，R3 和 R4 各自独立地是氢原子、C1 -C6 烷基或类似物，R5、R6、R7 和 R8 各自独立地是氢原子、卤素、C1 -C6 烷基或类似物，R9 是氢原子、C1 -C6 烷基或类似物，X 是卤素、C1 -C6 烷基或类似物。
• BIO-ELECTRODE COMPOSITION, BIO-ELECTRODE, AND METHOD FOR MANUFACTURING BIO-ELECTRODE
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20210371663A1

  公开（公告）日：2021-12-02

  A bio-electrode composition contains (A) an ionic polymer material. The component (A) is a polymer compound containing: a repeating unit-a having a structure selected from the group consisting of salts of ammonium, sodium, potassium, and silver formed with any of fluorosulfonic acid, fluorosulfonimide, and N-carbonyl-fluorosulfonamide; and a repeating unit-b having a side chain with a radical-polymerizable double bond in a structure selected from the group consisting of (meth)acrylate, vinyl ether, and styrene. Thus, the present invention provides: a bio-electrode composition capable of forming a living body contact layer for a bio-electrode to enable signal collection immediately after attachment to skin and prevention of residue on the skin after peeling from the skin; a bio-electrode including a living body contact layer formed of the bio-electrode composition; and a method for manufacturing the bio-electrode.
• [EN] MIXTURES OF HALOALKYLSULFONANILIDE DERIVATIVES AND HERBICIDES<br/>[FR] MÉLANGES DE DÉRIVÉS D'HALOALKYLSULFONANILIDE ET D'HERBICIDES
  申请人：SYNGENTA LTD

  公开号：WO2014184070A1

  公开（公告）日：2014-11-20

  The present invention relates to mixtures of herbicidal haloalkylsulfonanilide derivatives and a further herbicide.