N-(2-methyl-3-oxobutan-2-yl)-1-phenylmethanimine oxide | 123194-12-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2-methyl-3-oxobutan-2-yl)-1-phenylmethanimine oxide
• CAS: 123194-12-7
• 化学式: C₁₂H₁₅NO₂
• 分子量: 205.257
• InChiKey: MZLIDQXFRQSEOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(2-methyl-3-oxobutan-2-yl)-1-phenylmethanimine oxide 在 sodium tetrahydroborate 、 sodium hydride 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 1.42h， 生成
  参考文献：
  名称：

  Stable nitroxyl radicals with a hydrogen atom at ?-carbon atom of nitroxyl group

  摘要：

  Nitroxyl radicals containing the diphenylmethyl group as one of the substituents at the nitroxyl group are stable compounds that can be isolated in an individual state. N-(2-Hydroxy-3-methyl-2-phenylcyclohexyl)-N- diphenylmethylnitroxyl was characterized by X-ray diffraction analysis for the first time.

  DOI：

  10.1007/bf01433978
• 作为产物：
  描述：

  2-hydroxylamino-2-methyl-3-oxobutane 、 苯甲醛 在 sodium methylate 作用下， 以 甲醇 为溶剂， 以90%的产率得到N-(2-methyl-3-oxobutan-2-yl)-1-phenylmethanimine oxide
  参考文献：
  名称：

  Stable nitroxyl radicals with a hydrogen atom at ?-carbon atom of nitroxyl group

  摘要：

  Nitroxyl radicals containing the diphenylmethyl group as one of the substituents at the nitroxyl group are stable compounds that can be isolated in an individual state. N-(2-Hydroxy-3-methyl-2-phenylcyclohexyl)-N- diphenylmethylnitroxyl was characterized by X-ray diffraction analysis for the first time.

  DOI：

  10.1007/bf01433978

文献信息

• Stable nitroxyl radicals with a hydrogen atom at ?-carbon atom of nitroxyl group
  作者：V. A. Reznikov、I. A. Gulorov、Yu. V. Gatilov、T. V. Rybalova、L. B. Volodarsky

  DOI：10.1007/bf01433978

  日期：1996.2

  Nitroxyl radicals containing the diphenylmethyl group as one of the substituents at the nitroxyl group are stable compounds that can be isolated in an individual state. N-(2-Hydroxy-3-methyl-2-phenylcyclohexyl)-N- diphenylmethylnitroxyl was characterized by X-ray diffraction analysis for the first time.