2-(2-chlorophenoxy)-N'-(2-hydroxybenzylidene)acetohydrazide | 409348-89-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-(2-chlorophenoxy)-N'-(2-hydroxybenzylidene)acetohydrazide
• 英文别名: (2-chlorophenoxy)-N’-(2-hydroxybenzylidene)acetohydrazide；2-(2-chlorophenoxy)-N-[(2-hydroxyphenyl)methylideneamino]acetamide
• CAS: 409348-89-6
• 化学式: C₁₅H₁₃ClN₂O₃
• 分子量: 304.733
• InChiKey: GNYAEMMQJLLNTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  21
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  70.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  吗啉 、 2-(2-chlorophenoxy)-N'-(2-hydroxybenzylidene)acetohydrazide 、 copper diacetate 以 N,N-二甲基甲酰胺 为溶剂， 以78%的产率得到catena-poly[[[2-(2-chlorophenoxy)-N'-(2-oxidobenzylidene-κO)acetohydrazidato-κ²N',O]copper(II)]-μ-morpholine-κ²N:O]
  参考文献：
  名称：

  catena-Poly[[[2-(2-chlorophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ²N′,O]copper(II)]-μ-morpholine-κ²N:O]

  摘要：

  在标题化合物{[Cu(C15H11ClN2O3)(C4H9NO)]n中，CuII阳离子具有方锥几何结构。吗啉配体是连接两个对称性相关金属原子的桥梁，从而形成沿轴向的无限链结构。相邻的链通过吗啉和酰胺 N 原子间形成的氢键 [N-H...N = 2.971 (3) Å] 延伸成二维分层结构。

  DOI：

  10.1107/s0108270113011967

文献信息

• Synthesis, Crystal Structures, and Characterization of Three Novel Copper Complexes Based on N-acylsalicylhydrazone and Different Secondary Ligands
  作者：Min Wang、Zhaoxun Lian

  DOI：10.1080/15533174.2013.818028

  日期：2015.8.3

  The reactions of copper acetate and (2-hydroxybenzylidene)-2-phenylacetohydrazide (L1) and/or (2-chlorophenoxy)-N'-(2-hydroxybenzylidene) acetohydrazide (L2) in the presence of different secondary ligands, piperazine (pipe), pyridine (Py), and urotropine (Ur), in the solution of methanol and dimethyl formamide (V:V = 10:2) yielded three novel copper complexes, formulated as [CuL1](2)(pipe)2DMF 1, [Cu(Py)(L2)](2) 2, and [Cu(L2)](Ur).DMF 3, respectively. These three compounds have been characterized structurally using single-crystal diffraction. In 1, the copper complexes are bridged by pipe ligands to result in dimers. The pipe ligand serves as a (2) bridge. In 2, two square-pyramids Cu(N2O3) polyhedrons share a common edge to form a dinuclear compound. In 3, the copper complexes are linked by Ur ligands to result in the formation of chain structure. The three compound exhibit similar luminescence at (max) = 440, 460, and 680nm upon excitation at 354nm, respectively.