Cobalt-Catalyzed Asymmetric Reductive Dicarbofunctionalization of 1,3-Dienes with <i>o</i>-Bromoaryl Imines as a Bis-Electrophile
作者:Decai Ding、Linchuan Zhang、Hao Wen、Chuan Wang
DOI:10.1021/acscatal.2c05438
日期:2023.1.6
2-dicarbofunctionalization of 1,3-dienes employing o-bromoaryl imines as a bis-electrophilic coupling partner. This method provides an entry to prepare disubstituted cis-indanes in high diastereo- and enantioselectivities under mild reaction conditions. The proposed reaction mechanism consists of enantioselective intermolecular migratory insertion and diastereoselective intramolecular allylation as the key
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