申请人:FUJI PHOTO FILM CO., LTD.
公开号:EP0295698A2
公开(公告)日:1988-12-21
There are provided by the invention silver halide photographic light-sensitive materials containing dyestuff(s) represented by the general formula (I):
wherein R¹, R³, R⁴, R⁶, L₁, L₂, L₃, Z¹ and Z² are groups conventional in this technical field, and R² and R⁵ each represent an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted heterocyclic group, COR⁷ or SO₂R⁷ (wherein R⁷ represents an optionally substituted alkyl group or an optionally substituted aryl group) (including the case where the dyestuff(s) is(are) in the form of salt(s)).
The dyestuff(s) act(s) as a coloring agent for colored layer(s) for color filtering, antihalation, antiirradiation, etc.
Silver halide photographic light-sensitive materials containing dyestuffs represented by the general formula (I) of the invention have remarkable effects, for example, that stability of dyestuffs in the membrane with time lapse is high, relative sensitivity is high, lowering of sensitivity in exposure to light under high humidity is small, image quality is excellent, there is only a little remaining color, and/or there is only a little fog, as compared with silver halide photographic light-sensitive materials containing conventional dyestuffs for the aforementioned purposes.
本发明提供了含有通式(I)代表的染料的卤化银感光材料:
其中 R¹、R³、R⁴、R⁶、L₁、L₂、L₃、Z¹ 和 Z² 为本技术领域的常规基团,R² 和 R⁵ 分别代表任选取代的烷基、任选取代的芳基、任选取代的杂环基、COR⁷ 和 R⁸ 、任选取代的杂环基、COR⁷ 或 SO₂R⁷(其中 R⁷ 代表任选取代的烷基或任选取代的芳基)(包括染料以盐的形式存在的情况)。
染料可作为有色层的着色剂,用于滤色、防光、防辐射等。
含有本发明通式(I)所代表的染料的卤化银感光材料具有显著的效果,例如,与含有用于上述目的的传统染料的卤化银感光材料相比,染料在膜中随时间推移的稳定性高、相对感光度高、在高湿度下曝光时感光度降低小、图像质量优异、仅有少量残留色和/或仅有少量雾。