olivoretin B

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: olivoretin B
• 英文别名: Olivoretin B；(6S,9S,14S,17R)-17-ethenyl-6-(methoxymethyl)-10,14,17-trimethyl-9,14-di(propan-2-yl)-2,7,10-triazatetracyclo[9.7.1.04,19.013,18]nonadeca-1(18),3,11(19),12-tetraen-8-one
• 化学式: C₂₉H₄₃N₃O₂
• 分子量: 465.679
• InChiKey: HQINLFPKZPQGGD-HRLBTMOQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  34
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  57.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  olivoretin B 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 生成 (-)-teleocidin B-1
  参考文献：
  名称：

  Isolation and structure elucidation of teleocidin B-1, B-2, B-3, and B-4.

  摘要：

  From the mycelia of Streptomyces mediocidicus four metabolites teleocidin B-1, B-2, B-3 and B-4 were isolated in crystalline states and their structures were determined by comparison with the known des-O-methylolivoretin B, and olivoretin D (teleocidin B of Hirata), and by studying the 13C-nuclear magnetic resonance (NMR) spectra.

  DOI：

  10.1248/cpb.32.4233

文献信息

• Isolation and structure elucidation of teleocidin B-1, B-2, B-3, and B-4.
  作者：Yukio Hitotsuyanagi、Hirota Fujiki、Masami Suganuma、Norio Aimi、Shinichiro Sakai、Yasuyuki Endo、Koichi Shudo、Takashi Sugimura

  DOI：10.1248/cpb.32.4233

  日期：——

  From the mycelia of Streptomyces mediocidicus four metabolites teleocidin B-1, B-2, B-3 and B-4 were isolated in crystalline states and their structures were determined by comparison with the known des-O-methylolivoretin B, and olivoretin D (teleocidin B of Hirata), and by studying the 13C-nuclear magnetic resonance (NMR) spectra.