申请人:COURTAULDS PLC
公开号:EP0040080A2
公开(公告)日:1981-11-18
Nylon 6 polymer particles are made by a melt polymerisation process in which a polyether derived from one or more alkylene oxides is incorporated in the polymerisation melt so that the nylon 6 polymer is formed as particles in a matrix of the polyether. The particles may be recovered by dissolving away the matrix of polyether, and tend to be spheroidal in shape with an average particle size in the range 5 to 1,000 microns. Polyether concentrations of 15 per cent or more, preferably 20 to 30 per cent, by weight (based upon monomer(s) plus polyether) are used where particles as such are required, but polyether concentrations below 15 per cent by weight are used where it is desired to extrude the molten polymerisate to elongate the particles into fibres. On removal of the polyether matrix, a fibrous structure is produced which is yarn-like when the extrudate is a rod.
尼龙 6 聚合物颗粒是通过熔融聚合工艺制成的,在该工艺中,聚合熔体中加入了一种或多种氧化烯衍生的聚醚,这样尼龙 6 聚合物就在聚醚基体中形成了颗粒。这些颗粒可以通过溶解聚醚基质来回收,通常呈球形,平均粒径在 5 到 1,000 微米之间。聚醚浓度为 15%或更高,最好为 20%至 30%(以单体加聚醚为基准)(按重量计),用于需要颗粒的地方,但聚醚浓度低于 15%(按重量计),则用于需要挤出熔融聚合物将颗粒拉长成纤维的地方。除去聚醚基质后,会产生纤维结构,当挤出物为棒状时,其结构类似纱线。