5-降冰片烯-2-甲醇丙烯酸酯 | 95-39-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 5-降冰片烯-2-甲醇丙烯酸酯
• 英文名称: 2-Propenoic acid, bicyclo[2.2.1]hept-5-en-2-ylmethyl ester
• 英文别名: 2-bicyclo[2.2.1]hept-5-enylmethyl prop-2-enoate
• CAS: 95-39-6
• 化学式: C₁₁H₁₄O₂
• mdl: MFCD24393528
• 分子量: 178.23
• InChiKey: IEOVKCGOIXZDRK-UHFFFAOYSA-N

物化性质

• 沸点：
  270.46°C (rough estimate)
• 密度：
  1.0292 (rough estimate)
• 颜色/状态：
  Colorless liquid
• 溶解度：
  Sol in most organic solvents
• 聚合：
  METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER. /METHACRYLATES/

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.545
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

ADMET

毒理性

• 副作用

皮肤致敏剂 - 一种可以诱导皮肤产生过敏反应的制剂。

Skin Sensitizer - An agent that can induce an allergic reaction in the skin.

来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

制备方法与用途

类别：有毒物品

毒性分级：中毒

急性毒性：

• 口服 - 大鼠 LD50: 1410 毫克/公斤
• 皮肤接触 - 兔子 LD50: 2830 毫克/公斤

可燃性危险特性：可燃，燃烧时会产生刺激烟雾

储运特性：通风、低温、干燥

灭火剂：干粉、泡沫、沙土、二氧化碳、雾状水

文献信息

• Directly photodefinable polymer compositions and methods thereof
  申请人：Elce Edmund

  公开号：US20050186502A1

  公开（公告）日：2005-08-25

  The present invention relates to a directly photoimageable polymer composition (DPPC) and methods for its use in forming microelectronic and optoelectronic devices. Such DPPC encompasses a polymer having at least one norbornene-type repeat unit having a pendant silyl containing radical and at least one norbornene-type repeat unit having an acrylate containing radical.

  本发明涉及直接可光刻聚合物组合物（DPPC）及其在形成微电子和光电子器件中的使用方法。该DPPC包括具有至少一个含有硅基官能团的诺伯伦型重复单元和至少一个含有丙烯酸酯官能团的诺伯伦型重复单元的聚合物。
• Process for producing a molded article of metathesis polymerized polymer
  申请人：HERCULES INCORPORATED

  公开号：EP0305933A2

  公开（公告）日：1989-03-08

  A process for producing a cross-linked molded article by metathesis polymerizing in a mold a mixture comprising metathesis polymerizable monomers such as dicyclo­pentadiene and polymers having norbornene-group in the structure, the molded article and a polymerizable composition therefor.

  一种在模具中通过偏聚法聚合由偏聚单体（如双环戊二烯）和结构中含有降冰片烯基的聚合物组成的混合物，生产交联成型品的工艺，成型品及其可聚合组合物。
• Process for the in-line polymerization of olefinic monomers
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0694575A1

  公开（公告）日：1996-01-31

  A process for making a poly(olefin) film that involves the in-line polymerization of olefinic monomer(s) and catalyst systems comprising a transition metal species that mediates the polymerization of the monomer(s) is disclosed. A substrate is coated with a layer of a mixture comprising the olefinic monomer(s) and the catalyst and then the monomer(s) is(are) allowed to polymerize. This process provides the immediate use of the resultant polymer without extensive further processing.

  本发明公开了一种制造聚（烯烃）薄膜的工艺，该工艺涉及烯烃单体和催化剂系统的在线聚合，催化剂系统包括一种过渡金属，可介导单体的聚合。在基材上涂上一层由烯烃单体和催化剂组成的混合物，然后让单体聚合。这种工艺可立即使用生成的聚合物，而无需进行大量的进一步加工。
• Method for preparing modified resins and their applications
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0698620A1

  公开（公告）日：1996-02-28

  There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin. According to the preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins. By the utilization of these techniques, there can be obtained a flame-retardant material having a good char formability, a thermally stable material whose molded articles can inhibit heat deterioration, a material excellent in miscibility between different kinds of resins, a surface-modified material which is excellent in adhesion and coating properties and the like.

  本发明公开了一种制备改性树脂的方法，该方法包括通过使用以降冰片烯碳胍胺或其衍生物为代表的含降冰片烯基化合物进行热/反应；一种制备环氧改性树脂的方法，该方法包括使上述改性树脂与环氧化物反应的步骤、包括利用改性树脂的阻燃方法、热稳定方法、相容方法和表面改性方法，以及含有改性树脂的涂料树脂组合物和粘合剂树脂组合物。 根据本发明的制备方法，材料几乎不会变质，而且可以在树脂中引入阻燃性、热稳定性、相容性等性能优异的官能团。利用这些技术，可以获得一种具有良好炭化成型性的阻燃材料、一种热稳定性材料（其成型制品可抑制热变质）、一种在不同种类树脂之间具有良好混溶性的材料、一种在粘附性和涂覆性等方面具有良好性能的表面改性材料。
• Contact metathesis polymerization
  申请人：LORD CORPORATION

  公开号：EP1605006A1

  公开（公告）日：2005-12-14

  A method for providing a coating on a metal substrate surface comprising providing a metathesis catalyst at the metal substrate surface; and subsequently contacting said catalyst on the metal substrate surface with a coating of a material that undergoes a metathesis reaction, and forming a coating on said substrate surface from the product of said metathesis reaction.

  一种在金属基底表面提供涂层的方法，包括在金属基底表面提供偏析催化剂；随后将金属基底表面的所述催化剂与发生偏析反应的材料涂层接触，并利用所述偏析反应的产物在所述基底表面形成涂层。