N,N'-bis(2,6-diisopropylphenyl)-1,7-bis[4-(2-aminoethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid bisimide | 400780-05-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis(2,6-diisopropylphenyl)-1,7-bis[4-(2-aminoethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid bisimide
• 英文别名: N,N'-bis(2,6-diisopropylphenyl)-1,7-di[4-(2-aminoethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid diimide；11,22-Bis[4-(2-aminoethyl)phenoxy]-7,18-bis[2,6-di(propan-2-yl)phenyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-6,8,17,19-tetrone
• CAS: 400780-05-4
• 化学式: C₆₄H₆₀N₄O₆
• 分子量: 981.204
• InChiKey: ZWVZSFPPQUIRAY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  74
• 可旋转键数：
  14
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  145
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  N,N'-bis(2,6-diisopropylphenyl)-1,7-bis[4-(2-aminoethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid bisimide 、 十六烷基异氰酸酯 以 二氯甲烷 为溶剂， 反应 6.0h， 以79%的产率得到N,N'-bis(2,6-diisopropylphenyl)-1,7-bis{4-[2-(3-hexadecylureido)ethyl]phenoxy}perylene-3,4,9,10-tetracarboxylic acid bisimide
  参考文献：
  名称：

  Assembly and Characterization of Novel Hydrogen-Bond-Induced Nanoscale Rods

  摘要：

  A class of bis-urea compounds with perylene bisimide was synthesized and characterized successfully. H-1 NMR and fluorescence spectra confirmed that strong hydrogen-bonding interactions between neighboring urea groups were formed. Interestingly, the photocurrent measurement showed that the self-assembled films of bis-urea compounds could produce steady and rapid anodic photocurrent responses. The TEM images indicated that well-defined nanoscale rods with uniform diameter distribution, could be fabricated by self-assembly of hydrogen-bonding interactions and pi-pi stacking interactions of perylene rings.

  DOI：

  10.1021/jo0486037
• 作为产物：
  描述：

  N,N'-bis(2,6-diisopropylphenyl)-1,7-bis{4-[2-(tert-butoxycarbonylamino)ethyl]phenoxy}perylene-3,4,9,10-tetracarboxylic acid bisimide 在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以95%的产率得到N,N'-bis(2,6-diisopropylphenyl)-1,7-bis[4-(2-aminoethyl)phenoxy]perylene-3,4,9,10-tetracarboxylic acid bisimide
  参考文献：
  名称：

  Assembly and Characterization of Novel Hydrogen-Bond-Induced Nanoscale Rods

  摘要：

  A class of bis-urea compounds with perylene bisimide was synthesized and characterized successfully. H-1 NMR and fluorescence spectra confirmed that strong hydrogen-bonding interactions between neighboring urea groups were formed. Interestingly, the photocurrent measurement showed that the self-assembled films of bis-urea compounds could produce steady and rapid anodic photocurrent responses. The TEM images indicated that well-defined nanoscale rods with uniform diameter distribution, could be fabricated by self-assembly of hydrogen-bonding interactions and pi-pi stacking interactions of perylene rings.

  DOI：

  10.1021/jo0486037

文献信息

• Assembly and Characterization of Novel Hydrogen-Bond-Induced Nanoscale Rods
  作者：Yang Liu、Yongjun Li、Li Jiang、Haiyang Gan、Huibiao Liu、Yuliang Li、Junpeng Zhuang、Fushen Lu、Daoben Zhu

  DOI：10.1021/jo0486037

  日期：2004.12.1

  A class of bis-urea compounds with perylene bisimide was synthesized and characterized successfully. H-1 NMR and fluorescence spectra confirmed that strong hydrogen-bonding interactions between neighboring urea groups were formed. Interestingly, the photocurrent measurement showed that the self-assembled films of bis-urea compounds could produce steady and rapid anodic photocurrent responses. The TEM images indicated that well-defined nanoscale rods with uniform diameter distribution, could be fabricated by self-assembly of hydrogen-bonding interactions and pi-pi stacking interactions of perylene rings.