3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octane-1-sulfonic acid (2-hydroxy-ethyl)-methyl-amide | 51619-73-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octane-1-sulfonic acid (2-hydroxy-ethyl)-methyl-amide
• 英文别名: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoro-N-(2-hydroxyethyl)-N-methyl-1-octanesulfonamide；3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-N-(2-hydroxyethyl)-N-methyloctane-1-sulfonamide
• CAS: 51619-73-9
• 化学式: C₁₁H₁₂F₁₃NO₃S
• 分子量: 485.266
• InChiKey: PYEYQMPFVPJZMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66
• 氢给体数：
  1
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octane-1-sulfonic acid (2-hydroxy-ethyl)-methyl-amide 在 氯化亚砜 作用下， 以 甲苯 为溶剂， 反应 0.5h， 生成 N-(2-chloroethyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-N-methyloctane-1-sulfonamide
  参考文献：
  名称：

  [EN] MIXTURE OF POLYFLUOROALKYLSULFONAMIDO ALKYL AMINES
  [FR] MÉLANGE DE POLYFLUOROALKYLSULFONAMIDOALKYLAMINES

  摘要：

  本发明涉及一种聚氟烷基磺酰胺烷基胺混合物，包括至少一种聚氟烷基磺酰胺烷基胺及其类似物，即二(聚氟烷基磺酰胺烷基)胺。该发明还涉及用于制备上述混合物的聚氟烷基磺酰胺烷基卤代物中间体。

  公开号：

  WO2011119560A1

文献信息

• FLUOROSILANES
  申请人：Herzog Axel Hans-Joachim

  公开号：US20090143598A1

  公开（公告）日：2009-06-04

  Fluoroalkyl silanes are a class of compounds useful for various industrial purposes. For example, fluoroalkyl silanes which have hydrolysable groups (called hydrolysable fluoroalkyl silanes), are compounds useful as surface treatment agents which provide durable hydrophobic and oleophobic coatings. In general, hydrolysable fluoroalkyl silanes can be represented with the following formula: (RO—) 3 Si—R T wherein R is H or an alkyl; and R T is a monovalent organic compound terminated by a perfluoroalkyl group. When used to coat a surface, the (RO—) 3 moiety reacts (via hydrolysis) with various chemical groups of the surface (e.g., hydroxyl, amine, or other reactive groups) thereby bonding the fluoroalkyl silane to the surface The R T moiety comprises a divalent organic linking group which links the silicon atom to a terminal group rich in fluorine atoms whose unique electronic properties impart desirable hydrophobic and oleophobic properties in a surface coating. Modification of the R T moiety is useful in the engineering of fluoroalkyl silanes. The present invention provides for fluoroalkyl silanes having R T moieties which have not been heretofore considered.

  氟烷基硅烷是一类在各种工业用途中有用的化合物。例如，具有可水解基团（称为可水解氟烷基硅烷）的氟烷基硅烷是作为表面处理剂有用的化合物，可以提供耐久的疏水和疏油涂层。通常，可水解氟烷基硅烷可以用以下公式表示：(RO—)₃Si—RT，其中R为H或烷基；RT是以全氟烷基基团为末端的一价有机化合物。当用于涂覆表面时，(RO—)₃基团通过水解与表面的各种化学基团（如羟基、胺基或其他反应性基团）发生反应，从而将氟烷基硅烷与表面结合。RT基团包括一种双价有机连接基团，将硅原子与富含氟原子的末端基团连接起来，其独特的电子性质赋予涂层中理想的疏水和疏油性能。对RT基团的修改对于工程氟烷基硅烷是有用的。本发明提供了具有未被考虑过的RT基团的氟烷基硅烷。
• [EN] MIXTURE OF POLYFLUOROALKYLSULFONAMIDO ALKYL AMINES<br/>[FR] MÉLANGE DE POLYFLUOROALKYLSULFONAMIDOALKYLAMINES
  申请人：DU PONT

  公开号：WO2011119560A1

  公开（公告）日：2011-09-29

  The present invention relates to a mixture of polyfluoroalkylsulfonamido alkyl amines including at least one polyfluoroalkylsulfonamido alkyl amine and its analog, a di(polyfluoroalkylsulfonamido alkyl) amine. The invention also relates to polyfluoroalkylsulfonamido alkyl halide intermediate used to make the aforementioned mixture.

  本发明涉及一种聚氟烷基磺酰胺烷基胺混合物，包括至少一种聚氟烷基磺酰胺烷基胺及其类似物，即二(聚氟烷基磺酰胺烷基)胺。该发明还涉及用于制备上述混合物的聚氟烷基磺酰胺烷基卤代物中间体。
• POLYFLUOROALKYLSULFONAMIDO ALKYL HALIDE INTERMEDIATE
  申请人：Shtarov Alexander Borisovich

  公开号：US20110237834A1

  公开（公告）日：2011-09-29

  The present invention relates to a polyfluoroalkylsulfonamido alkyl halide intermediate. The invention also relates to the use of the aforementioned halide intermediate to prepare a mixture of polyfluoroalkylsulfonamido alkyl amines including at least one polyfluoroalkylsulfonamido alkyl amine and its analog, a di(polyfluoroalkylsulfonamido alkyl) amine.

  本发明涉及一种聚氟烷磺酰胺烷基卤代物中间体。该发明还涉及利用上述卤代物中间体制备一种聚氟烷磺酰胺烷基胺混合物，其中至少包括一种聚氟烷磺酰胺烷基胺及其类似物，即二(聚氟烷磺酰胺烷基)胺。