1-methoxy-2-indanone | 76177-04-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 1-methoxy-2-indanone
• 英文别名: 1-Methoxy-1,3-dihydroinden-2-one
• CAS: 76177-04-3
• 化学式: C₁₀H₁₀O₂
• 分子量: 162.188
• InChiKey: QXEUBYSXDLFUOS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-acetoxy-2-indanone 、 盐酸 生成 1-methoxy-2-indanone
  参考文献：
  名称：

  HATSUI TOSHIHIDE; TAKESHITA HITOSHI, BULL. CHEM. SOC. JAP., 1980, 53, NO 9, 2655-2658

  摘要：

  DOI：

文献信息

• Photochemical reactions of alkoxy-containing-alkyl phenylglyoxylates: remote hydrogen abstraction
  作者：Shengkui Hu、D. C. Neckers

  DOI：10.1039/a700948h

  日期：——

  A series of alkoxy-containing-alkyl phenylglyoxylates have been synthesized and their photochemical reactions studied. The intention was to probe structural requirements for remote hydrogen abstraction. Products resulting from 1,10- and 1,11-hydrogen abstraction were isolated from the photochemical reactions of 4′-methoxybutyl phenylglyoxylate 3d and 5′-benzyloxypentyl phenylglyoxylate 3h respectively. Products resulting from Norrish Type II and intermolecular hydrogen abstraction reactions were also isolated. Triplet lifetimes of representative compounds were measured by laser flash photolysis.

  我们合成了一系列含烷氧基的烷基苯基乙醛酸酯，并研究了它们的光化学反应。分别从 4′-甲氧基丁基苯基乙醛酸酯 3d 和 5′-苄氧基戊基苯基乙醛酸酯 3h 的光化学反应中分离出了 1,10- 和 1,11- 氢抽取产物。此外，还分离出了诺里什 II 型反应和分子间氢抽离反应产生的产物。用激光闪烁光解法测量了代表性化合物的三重寿命。
• Synthetic Photochemistry. XVIII. A Sensitizer Dependence in the Photooxidation of Indene and Acenaphthylene. The Occurrence of<i>cis</i>-1,2-Glycol Formation in a Rose Bengal-sensitized Reaction
  作者：Toshihide Hatsui、Hitoshi Takeshita

  DOI：10.1246/bcsj.53.2655

  日期：1980.9

  Upon Rose Bengal-sensitized photooxygenation, indene and acenaphthylene afforded substantial amounts of the expected cis-glycols by means of the reduction of the intermediate dioxetanes. The formerly proposed structure of one of the isomeric methoxy hydroperoxides was revised on the basis of the chemical and spectral evidence.

  在玫瑰红敏化光氧合作用下，茚和苊通过中间二氧杂环丁烷的还原作用生成了大量预期的顺式乙二醇。根据化学和光谱证据，对以前提出的其中一种异构体甲氧基过氧化氢的结构进行了修改。
• HATSUI TOSHIHIDE; TAKESHITA HITOSHI, BULL. CHEM. SOC. JAP., 1980, 53, NO 9, 2655-2658
  作者：HATSUI TOSHIHIDE、 TAKESHITA HITOSHI

  DOI：——

  日期：——