3-(3-Hydroxy-2,2-dinitro-propoxymethoxy)-2,2-dinitro-propan-1-ol | 14674-58-9

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: 3-(3-Hydroxy-2,2-dinitro-propoxymethoxy)-2,2-dinitro-propan-1-ol
• 英文别名: 3,3'-[Methylenebis(oxy)]bis(2,2-dinitropropan-1-ol)；3-[(3-hydroxy-2,2-dinitropropoxy)methoxy]-2,2-dinitropropan-1-ol
• CAS: 14674-58-9
• 化学式: C₇H₁₂N₄O₁₂
• 分子量: 344.192
• InChiKey: BBFSNKVOKLXPJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.9
• 重原子数：
  23
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  242
• 氢给体数：
  2
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  3-(3-Hydroxy-2,2-dinitro-propoxymethoxy)-2,2-dinitro-propan-1-ol 、 2-fluoro-2,2-dinitroethyl isocyanate 在 吡啶 作用下， 以 二氯甲烷 为溶剂， 生成 (2-Fluoro-2,2-dinitro-ethyl)-carbamic acid 3-[3-(2-fluoro-2,2-dinitro-ethylcarbamoyloxy)-2,2-dinitro-propoxymethoxy]-2,2-dinitro-propyl ester
  参考文献：
  名称：

  Fluoronitroaliphatics. VI. Preparation of N-(2,2,2-fluorodinitroethyl)amides

  摘要：

  DOI：

  10.1021/jo00970a018

文献信息

• 1:3 "mixed" polynitroethyl orthocarbonates from
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US04705899A1

  公开（公告）日：1987-11-10

  1:3 "mixed" orthocarbonates of the formula [CF(NO.sub.2).sub.2 CH.sub.2 O].sub.3 C--OR wherein R is --CH.sub.2 C(NO.sub.2).sub.3, --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3, --CH.sub.2 CH.sub.2 NO.sub.2, --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH, --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OC[OCH.sub.2 CF(NO.sub.2).sub.2 ].s3, --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH, --CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OC[OCH.sub.2 CF(NO.sub.2).sub.2 ].sub.3, --CH.sub.2 CF.sub.3, --CH.sub.2 CH.sub.3, and ##STR1## and a method of preparation.

  该文提供了一种公式为[CF(NO.sub.2).sub.2 CH.sub.2 O].sub.3 C--OR的“混合”正碳酸酯，其中R为--CH.sub.2 C(NO.sub.2).sub.3，--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.3，--CH.sub.2 CH.sub.2 NO.sub.2，--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH，--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OC[OCH.sub.2 CF(NO.sub.2).sub.2 ].s3，--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OH，--CH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OCH.sub.2 OCH.sub.2 C(NO.sub.2).sub.2 CH.sub.2 OC[OCH.sub.2 CF(NO.sub.2).sub.2 ].sub.3，--CH.sub.2 CF.sub.3，--CH.sub.2 CH.sub.3和##STR1##，以及一种制备方法。
• Methods of producing energetic polymers, energetic binders, and energetic compositions
  申请人：Northrop Grumman Innovation Systems, Inc.

  公开号：US10696786B2

  公开（公告）日：2020-06-30

  A method of producing an energetic polymer comprises reacting at least one energetic diol with at least one of a diacid halide and a diacid halide derivative to produce a geminal dinitro polyester. A method of producing an energetic binder, and a method of producing an energetic composition are also described.

  一种生产高能聚合物的方法包括使至少一种高能二元醇与二元酸卤化物和二元酸卤化物衍生物中的至少一种发生反应，生成一种宝石二硝基聚酯。还描述了一种生产高能粘合剂的方法和一种生产高能组合物的方法。
• METHODS OF PRODUCING ENERGETIC POLYMERS, ENERGETIC BINDERS, AND ENERGETIC COMPOSITIONS
  申请人：Orbital ATK, Inc.

  公开号：US20160168317A1

  公开（公告）日：2016-06-16

  A method of producing an energetic polymer comprises reacting at least one energetic diol with at least one of a diacid halide and a diacid halide derivative to produce a geminal dinitro polyester. A method of producing an energetic binder, and a method of producing an energetic composition are also described.
• US3878004A
  申请人：——

  公开号：US3878004A

  公开（公告）日：1975-04-15
• US4705899A
  申请人：——

  公开号：US4705899A

  公开（公告）日：1987-11-10