N-[4-(2-ethylhexyloxy)-3,5-dimethylphenyl]carbazole | 911001-01-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: N-[4-(2-ethylhexyloxy)-3,5-dimethylphenyl]carbazole
• 英文别名: 9-(4-(2-ethylhexyloxy)-3,5-dimethyl-phenyl)carbazole；9-[4-(2-Ethylhexoxy)-3,5-dimethylphenyl]carbazole；9-[4-(2-ethylhexoxy)-3,5-dimethylphenyl]carbazole
• CAS: 911001-01-9
• 化学式: C₂₈H₃₃NO
• 分子量: 399.576
• InChiKey: LOGTXDQDENREDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  30
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  14.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-[4-(2-ethylhexyloxy)-3,5-dimethylphenyl]carbazole 在 N-溴代丁二酰亚胺(NBS) 、 过氧化苯甲酰 作用下， 以 四氯化碳 为溶剂， 反应 4.0h， 以50%的产率得到N-[4-(2-ethylhexyloxy)-3,5-di(bromomethyl)phenyl]carbazole
  参考文献：
  名称：

  Synthesis and Electro-Optical Properties of Carbazole Containing Copolymers with Different Conjugated Structures for Polymer Light-Emitting Devices

  摘要：

  New copolymers such as Poly(9-(4-(2-ethyl-hexyloxy)-3,5-dimethylphenyl)carbazole-alt-aminonaphtalene) [P1] and Poly(4-(bis-methylbiphenyl-alt-9H-carbazol-9-yl)benzenamine) [P2] with chromophores separated by non-conjugated methylene spacers, and Poly(4-(dioctylfluorene-alt-9H-carbazole-9yl)benzenamine) [P3] based on alternating fluorene and amine units in the polymer backbone were synthesized by palladium catalyzed polycondensation reaction. Optical properties of these polymers were characterized in terms of UV/visible absorption and photoluminescence (PL) emission in solution and film state. Maximum PL emission (max,PL) of synthesized copolymers were observed in the blue region of 426nm-460nm in solution state, but the three polymers all showed large red shift in film state with the green emission. The electro-optical properties of these polymers in polymer light-emitting diode (PLED) devices were investigated from the viewpoint of utilizing the new polymers as emitting layer and hole injection/transport layer. The polymer P3 was found to function both as hole injection and hole transport layer with performance better than that of well known PEDOT:PSS hole injection layer material.

  DOI：

  10.1080/15421400802620030
• 作为产物：
  描述：

  4-溴-2,6-二甲基苯酚 在 氢氧化钾 、 potassium phosphate 、 copper(l) iodide 、 (1S,2S)-(+)-1,2-环己二胺 作用下， 以 1,4-二氧六环 、 乙腈 为溶剂， 反应 96.0h， 生成 N-[4-(2-ethylhexyloxy)-3,5-dimethylphenyl]carbazole
  参考文献：
  名称：

  Synthesis and Characterization of Poly(N-arylcarbazole-alt-aniline) Copolymers as Blue-Emitting Host Matrix for Polymer Light-Emitting Diodes

  摘要：

  DOI：

  10.1080/15421400600930417

文献信息

• Synthesis and Electro-Optical Properties of Carbazole Containing Copolymers with Different Conjugated Structures for Polymer Light-Emitting Devices
  作者：Jin Woo Kim、Eun Jung Park、Eon Joo Lyu、Yun-Su Lee、Younghwan Kwon、Lee Soon Park

  DOI：10.1080/15421400802620030

  日期：2009.2.25

  New copolymers such as Poly(9-(4-(2-ethyl-hexyloxy)-3,5-dimethylphenyl)carbazole-alt-aminonaphtalene) [P1] and Poly(4-(bis-methylbiphenyl-alt-9H-carbazol-9-yl)benzenamine) [P2] with chromophores separated by non-conjugated methylene spacers, and Poly(4-(dioctylfluorene-alt-9H-carbazole-9yl)benzenamine) [P3] based on alternating fluorene and amine units in the polymer backbone were synthesized by palladium catalyzed polycondensation reaction. Optical properties of these polymers were characterized in terms of UV/visible absorption and photoluminescence (PL) emission in solution and film state. Maximum PL emission (max,PL) of synthesized copolymers were observed in the blue region of 426nm-460nm in solution state, but the three polymers all showed large red shift in film state with the green emission. The electro-optical properties of these polymers in polymer light-emitting diode (PLED) devices were investigated from the viewpoint of utilizing the new polymers as emitting layer and hole injection/transport layer. The polymer P3 was found to function both as hole injection and hole transport layer with performance better than that of well known PEDOT:PSS hole injection layer material.
• Synthesis and Characterization of Poly(<i>N</i>-arylcarbazole-<i>alt</i>-aniline) Copolymers as Blue-Emitting Host Matrix for Polymer Light-Emitting Diodes
  作者：Hui Wang、Jeong-Tak Ryu、Yoon Soo Han、Dae-Hwan Kim、Byeong Dae Choi、Lee Soon Park、Dayong Teng、Younghwan Kwon

  DOI：10.1080/15421400600930417

  日期：2006.12