dimethylacetamide bromine complex

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: dimethylacetamide bromine complex
• 英文别名: N,N-dimethylacetamide;molecular bromine
• 化学式: Br₂*C₄H₉NO
• 分子量: 246.93
• InChiKey: ORYJPGUNAQPYRZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.79
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N,N-二甲基乙酰胺 在 溴 作用下， 生成 dimethylacetamide bromine complex
  参考文献：
  名称：

  摘要：

  N,N-Dialkylcarboxamides react with halogens in the absence of water to form complexes which are likely to have an ionic structure with the Hlg(+) ion coordinated at the carbonyl oxygen atom. These products can be isolated as individual compounds. Complexes with bromine undergo further transformations to afford bis-dialkylamide hydrogen tribromide and the corresponding a-bromo amide. When the reaction is carried out in the presence of water, the products are only bis-dialkylamide hydrogen tribromides; here, the N-alkyl groups act as a source of protons.

  DOI：

  10.1023/a:1013146630045

文献信息

• ——
  作者：N. I. Burakov、A. L. Kanibolotskii、G. Yu. Osichenko、V. A. Mikhailov、V. A. Savelova、V. V. Kosmynin

  DOI：10.1023/a:1013146630045

  日期：——

  N,N-Dialkylcarboxamides react with halogens in the absence of water to form complexes which are likely to have an ionic structure with the Hlg(+) ion coordinated at the carbonyl oxygen atom. These products can be isolated as individual compounds. Complexes with bromine undergo further transformations to afford bis-dialkylamide hydrogen tribromide and the corresponding a-bromo amide. When the reaction is carried out in the presence of water, the products are only bis-dialkylamide hydrogen tribromides; here, the N-alkyl groups act as a source of protons.