N,N'-bis[4-(9-phenyl-9H-fluoren-9-yl)phenyl]-N,N'-dinaphthylpyrene-1,6-diamine | 1292285-31-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: N,N'-bis[4-(9-phenyl-9H-fluoren-9-yl)phenyl]-N,N'-dinaphthylpyrene-1,6-diamine
• 英文别名: N,N'-bis[4-(9-phenyl-9H-fluoren-9-yl)phenyl]-N,N'-dinaphthyl-pyrene-1,6-diamine；1-N,6-N-dinaphthalen-1-yl-1-N,6-N-bis[4-(9-phenylfluoren-9-yl)phenyl]pyrene-1,6-diamine
• CAS: 1292285-31-4
• 化学式: C₈₆H₅₆N₂
• 分子量: 1117.4
• InChiKey: NZBNPPKRDCTBCH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  23.5
• 重原子数：
  88
• 可旋转键数：
  10
• 环数：
  18.0
• sp3杂化的碳原子比例：
  0.02
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,6-二溴芘 、 1-naphthyl-4-(9-phenyl-9H-fluoren-9-yl)phenylamine 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 三叔丁基膦 、 sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 1.8h， 以37%的产率得到N,N'-bis[4-(9-phenyl-9H-fluoren-9-yl)phenyl]-N,N'-dinaphthylpyrene-1,6-diamine
  参考文献：
  名称：

  Fluorene Derivative, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device

  摘要：

  公开号：

  EP2314565B1

文献信息

• FLUORENE DERIVATIVE, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：Ogita Kaori

  公开号：US20110095678A1

  公开（公告）日：2011-04-28

  An object is to provide a new fluorene derivative as a good light-emitting material for organic EL elements. A fluorene derivative represented by General Formula (G1) is provided. In the formula, R 1 to R 8 separately represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α 1 to α 4 separately represent a substituted or unsubstituted phenylene group. Ar 1 represents a substituted or unsubstituted condensed aromatic hydrocarbon having 14 to 18 carbon atoms forming a ring. Ar 2 represents a substituted or unsubstituted aryl group having 6 to 13 carbon atoms forming a ring. Ar 3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. Further, j, m, and n separately represent 0 or 1, and p represents 1 or 2.

  提供一种新的萘衍生物作为有机EL元件的良好发光材料的目的。提供了一种由通用式（G1）表示的萘衍生物。在该式中，R1至R8分别表示氢原子、具有1至6个碳原子的烷基基团、取代或未取代的苯基团，或取代或未取代的联苯基团。此外，α1至α4分别表示取代或未取代的苯基亚基团。Ar1表示具有14至18个碳原子形成环的取代或未取代的紧凑芳香烃。Ar2表示具有6至13个碳原子形成环的取代或未取代的芳基基团。Ar3表示具有1至6个碳原子的烷基基团或具有6至12个碳原子的取代或未取代的芳基基团。此外，j、m和n分别表示0或1，p表示1或2。
• Fluorene derivative, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Ogita Kaori

  公开号：US08642190B2

  公开（公告）日：2014-02-04

  An object is to provide a new fluorene derivative as a good light-emitting material for organic EL elements. A fluorene derivative represented by General Formula (G1) is provided. In the formula, R1 to R8 separately represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, or a substituted or unsubstituted biphenyl group. Further, α1 to α4 separately represent a substituted or unsubstituted phenylene group. Ar1 represents a substituted or unsubstituted condensed aromatic hydrocarbon having 14 to 18 carbon atoms forming a ring. Ar2 represents a substituted or unsubstituted aryl group having 6 to 13 carbon atoms forming a ring. Ar3 represents an alkyl group having 1 to 6 carbon atoms or a substituted or unsubstituted aryl group having 6 to 12 carbon atoms. Further, j, m, and n separately represent 0 or 1, and p represents 1 or 2.

  本发明旨在提供一种新的芴衍生物，作为有机EL元件的良好发光材料。提供了一种由通式（G1）表示的芴衍生物。在该式中，R1至R8分别表示氢原子，具有1至6个碳原子的烷基，取代或未取代的苯基，或取代或未取代的联苯基。此外，α1至α4分别表示取代或未取代的苯基。Ar1表示形成环的具有14至18个碳原子的取代或未取代的紧缩芳香烃。Ar2表示形成环的具有6至13个碳原子的取代或未取代的芳基。Ar3表示具有1至6个碳原子的烷基或具有6至12个碳原子的取代或未取代的芳基。此外，j，m和n分别表示0或1，p表示1或2。
• US8642190B2
  申请人：——

  公开号：US8642190B2

  公开（公告）日：2014-02-04
• US9553273B2
  申请人：——

  公开号：US9553273B2

  公开（公告）日：2017-01-24
• Fluorene Derivative, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：EP2314565B1

  公开（公告）日：2013-07-24