1-bromo-6-(naphthalen-1-yl) pyrene | 870774-30-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1-bromo-6-(naphthalen-1-yl) pyrene
• 英文别名: 1-Bromo-6-(naphthalen-1-yl)pyrene；1-bromo-6-naphthalen-1-ylpyrene
• CAS: 870774-30-4
• 化学式: C₂₆H₁₅Br
• 分子量: 407.309
• InChiKey: YPQPBSDSZQDAFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  27
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-bromo-6-(naphthalen-1-yl) pyrene 在 四(三苯基膦)钯 、 potassium acetate 、 sodium carbonate 作用下， 以 1,4-二氧六环 、 乙醇 、 甲苯 为溶剂， 反应 30.0h， 生成 4,4,5,5-tetramethyl-2-(4-(6-(naphthalen-1-yl)pyren-1-yl)phenyl)-1,3,2-dioxaborolane
  参考文献：
  名称：

  COMPOUND FOR ORGANIC ELECTROLUMINESCENT DEVICE

  摘要：

  本发明一般公开了一种有机化合物和使用该有机化合物的有机电致发光（以下简称为有机EL）器件。更具体地说，本发明涉及一种使用该有机化合物作为荧光发射主体或磷光发射主体的有机EL器件，该器件可以显示出长寿命和高效率。

  公开号：

  US20160218293A1
• 作为产物：
  描述：

  1,6-二溴芘 、 1-萘硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 24.0h， 以45.5%的产率得到1-bromo-6-(naphthalen-1-yl) pyrene
  参考文献：
  名称：

  INDENOTRIPHENYLENE DERIVATIVES AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME

  摘要：

  本发明公开了一种新的茚三苯衍生物以及使用这些衍生物的有机发光器件。采用新的茚三苯衍生物作为主体材料的有机发光器件可以降低驱动电压，延长半寿命，并提高效率。新的茚三苯衍生物由以下式（A）表示：其中A1，A2是具有一个至五个环的取代或未取代的融合环烃基。最好的情况是A1，A2是苯基，萘基，蒽基，芘基，芴基，蒽基或苝基。R1到R4是相同或不同的。R1到R4独立地选自由氢原子，卤素，具有1至20个碳原子的烷基，具有6至30个碳原子的取代或未取代的芳基，具有6至30个碳原子的取代或未取代的芳基烷基，具有6至30个碳原子的取代或未取代的杂芳基。X选自碳原子或氮原子。

  公开号：

  US20140131664A1

文献信息

• Asymmetric pyrene derivative and organic electroluminescence device employing the same
  申请人：Kubota Mineyuki

  公开号：US20060154107A1

  公开（公告）日：2006-07-13

  Asymmetric pyrene derivatives having specific structure. An organic EL device comprising at least one organic thin film layer including a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises at least one kind selected from the aforementioned asymmetric pyrene derivatives singly or as a component of mixture thereof. An organic EL device exhibiting a great efficiency of light emission and having a long lifetime, and also asymmetric pyrene derivatives for realizing the organic EL device are provided.

  具有特定结构的不对称芘衍生物。一种有机EL器件，包括至少一个有机薄膜层，其中包括一个发光层，夹在由阳极和阴极组成的一对电极之间，其中有机薄膜层包括从上述不对称芘衍生物中选择的至少一种，单独或作为混合物的组分。提供了一种具有高效发光和长寿命的有机EL器件，以及实现该有机EL器件的不对称芘衍生物。
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US20140175384A1

  公开（公告）日：2014-06-26

  The present invention discloses a novel material is represented by the following formula (A), the organic EL device employing the material as blue emitting layer can lower driving voltage, prolong half-lifetime and increase the efficiency. Wherein m represent an integer of 0 to 4, R 1 and R 2 are identical or different. R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms. R 3 and R 4 are identical or different, R 3 and R 4 are independently selected from the group consisting of hydrogen atom, a halide, a substituted or unsubstituted arylamine, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms.

  本发明公开了一种新型材料，其由以下式（A）所表示，采用该材料作为蓝色发射层的有机EL器件可以降低驱动电压，延长半寿命并增加效率。其中m表示0到4的整数，R1和R2相同或不同。R1和R2独立地选自由1到20个碳原子的烷基，具有6到30个碳原子的取代或未取代芳基，具有6到30个碳原子的取代或未取代芳基烷基的群。R3和R4相同或不同，R3和R4独立地选自氢原子，卤素，取代或未取代芳基胺，具有1到20个碳原子的取代或未取代烷基，具有6到30个碳原子的取代或未取代芳基的群。
• Material for organic electroluminescent device
  申请人：Luminescence Technology Corporation

  公开号：US08962160B2

  公开（公告）日：2015-02-24

  The present invention discloses a novel material is represented by the following formula (A), the organic EL device employing the material as blue emitting layer can lower driving voltage, prolong half-lifetime and increase the efficiency. Wherein m represent an integer of 0 to 4, R1 and R2 are identical or different. R1 and R2 are independently selected from the group consisting of a hydrogen atom, alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms. R3 and R4 are identical or different, R3 and R4 are independently selected from the group consisting of hydrogen atom, a halide, a substituted or unsubstituted arylamine, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms.

  本发明揭示了一种由以下公式（A）表示的新材料，采用该材料作为蓝色发射层的有机EL器件可以降低驱动电压，延长半衰期并提高效率。其中m表示0至4的整数，R1和R2相同或不同。R1和R2独立地选自由1至20个碳原子的烷基，具有6至30个碳原子的取代或未取代的芳基，具有6至30个碳原子的取代或未取代的芳基烷基。R3和R4相同或不同，R3和R4独立地选自氢原子，卤素，取代或未取代的芳基胺，具有1至20个碳原子的取代或未取代的烷基，具有6至30个碳原子的取代或未取代的芳基。
• Indenotriphenylene derivatives and organic light emitting device using the same
  申请人：LUMINESCENCE TECHNOLOGY CORPORATION

  公开号：US09260363B2

  公开（公告）日：2016-02-16

  The present invention discloses a new indenotriphenylene derivatives and an organic light emitting device using the derivative. The organic light emitting device employing the new indenotriphenylene derivative as host material can lower driving voltage, prolong half-lifetime, increasing efficiency. The new indenotriphenylene derivative is represented by the following formula(A): According to formula(A), A1, A2 are substituted or unsubstituted aromatic ring systems with one to five rings and independently selected from the group consisting of a phenyl group, a naphthyl group, an anthracenyl group, a pyrenyl group, a chrysenyl group and a perylenyl group. R1 to R4 are identical or different. R1 to R4 are independently selected from the group consisting of a hydrogen atom, a halide, an alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 carbon atoms and a substituted or unsubstituted heteroaryl group having 6 to 30 carbon atoms. X is selected from carbon atom or nitrogen atom.

  本发明揭示了一种新的茚三苯衍生物及其在有机发光器件中的应用。采用新的茚三苯衍生物作为主体材料的有机发光器件可以降低驱动电压，延长半衰期，提高效率。新的茚三苯衍生物由以下公式(A)表示：根据公式(A)，A1、A2是具有1到5个环的取代或未取代芳香环系统，可独立地选自苯基、萘基、蒽基、芘基、蒽醌基和苝基。R1到R4相同或不同，可独立地选自氢原子、卤素、具有1到20个碳原子的烷基、具有6到30个碳原子的取代或未取代芳基、具有6到30个碳原子的取代或未取代芳基烷基、以及具有6到30个碳原子的取代或未取代杂环芳基。X选自碳原子或氮原子。
• ASYMMETRIC PYRENE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE EMPLOYING THE SAME
  申请人：KUBOTA Mineyuki

  公开号：US20100308718A1

  公开（公告）日：2010-12-09

  Asymmetric pyrene derivatives having specific structure. An organic EL device comprising at least one organic thin film layer including a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein the organic thin film layer comprises at least one kind selected from the aforementioned asymmetric pyrene derivatives singly or as a component of mixture thereof. An organic EL device exhibiting a great efficiency of light emission and having a long lifetime, and also asymmetric pyrene derivatives for realizing the organic EL device are provided.

  具有特定结构的非对称芘衍生物。一种有机EL器件，包括至少一个有机薄膜层，其中包括夹在由阳极和阴极组成的一对电极之间的发光层，其中有机薄膜层包括上述非对称芘衍生物之一或其混合物组分。提供一种具有出色的发光效率和长寿命的有机EL器件，以及实现有机EL器件的非对称芘衍生物。