1-N,6-N-diphenyl-1-N,6-N-bis[4-(N-phenylanilino)phenyl]pyrene-1,6-diamine | 1193362-65-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1-N,6-N-diphenyl-1-N,6-N-bis[4-(N-phenylanilino)phenyl]pyrene-1,6-diamine
• CAS: 1193362-65-0
• 化学式: C₆₄H₄₆N₄
• 分子量: 871.096
• InChiKey: ZVPAGBANRMHJKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18
• 重原子数：
  68
• 可旋转键数：
  12
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,6-二溴芘 、 4-(苯基氨基)三苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以61%的产率得到1-N,6-N-diphenyl-1-N,6-N-bis[4-(N-phenylanilino)phenyl]pyrene-1,6-diamine
  参考文献：
  名称：

  Emission Color Tuning and Deep Blue Dopant Materials Based on 1,6-Bis(N-phenyl-p-(R)-phenylamino)pyrene

  摘要：

  Panchromatic 1,6-bis(N-phenyl-p-(R)-phenylamino)pyrenes, 2R, were obtained from Buchwald-Hartwig coupling reactions between N-phenyl-p-(R)-phenylamines and 1,6-dibromopyrene. The photophysical properties of 2R corresponded well to the electron-withdrawing and -donating nature of the diarylamine substituents, exhibiting a full color visible range between 454 and 620 nm. In particular, a deep blue 2CN showed a high radiative rate constant of 2.85 x 10(8) s(-1) with high emission quantum efficiency of 79%. Further applications of 2CN its it blue dopant were attempted using multilayer organic light-emitting devices. A maximum efficiency of 3.98 cd/A with CIE coordinates of x = 0.14, y = 0.10 were obtained.

  DOI：

  10.1021/jo901783a

文献信息

• Emission Color Tuning and Deep Blue Dopant Materials Based on 1,6-Bis(<i>N</i>-phenyl-<i>p</i>-(<i>R</i>)-phenylamino)pyrene
  作者：Kyung-Ryang Wee、Hyun-Chul Ahn、Ho-Jin Son、Won-Sik Han、Ju-Eun Kim、Dae Won Cho、Sang Ook Kang

  DOI：10.1021/jo901783a

  日期：2009.11.6

  Panchromatic 1,6-bis(N-phenyl-p-(R)-phenylamino)pyrenes, 2R, were obtained from Buchwald-Hartwig coupling reactions between N-phenyl-p-(R)-phenylamines and 1,6-dibromopyrene. The photophysical properties of 2R corresponded well to the electron-withdrawing and -donating nature of the diarylamine substituents, exhibiting a full color visible range between 454 and 620 nm. In particular, a deep blue 2CN showed a high radiative rate constant of 2.85 x 10(8) s(-1) with high emission quantum efficiency of 79%. Further applications of 2CN its it blue dopant were attempted using multilayer organic light-emitting devices. A maximum efficiency of 3.98 cd/A with CIE coordinates of x = 0.14, y = 0.10 were obtained.