π-Extended and Six-Coordinate Iron(II) Complexes: Structures, Magnetic Properties, and the Electrochemical Synthesis of a Conducting Iron(II) Metallopolymer
作者:Brandon Djukic、Takele Seda、Serge I. Gorelsky、Alan J. Lough、Martin T. Lemaire
DOI:10.1021/ic2010503
日期:2011.8
the resulting neutral, six-coordinatecomplexes were fully characterized, including with single crystal X-ray diffraction experiments in the case of complexes 7 and 9. Variable temperature magnetic susceptibility and Mössbauer experiments confirm the presence of spin-crossover in complexes 7 and 8, and the unusual solid state variable temperature magneticproperties of complex 9 likely result from crystal