7'-(dimethylamino)-4,4-dimethyl-2'-phenylspiro[3H-pyrano[3,2-c]chromene-2,4'-chromene]-5-one | 1072902-47-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• 英文名称: 7'-(dimethylamino)-4,4-dimethyl-2'-phenylspiro[3H-pyrano[3,2-c]chromene-2,4'-chromene]-5-one
• CAS: 1072902-47-6
• 化学式: C₃₀H₂₇NO₄
• 分子量: 465.549
• InChiKey: KHIWCBWINCXPSJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  35
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  48
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4-羟基香豆素 、 7-N,N-dimethylamino-4-methylflavylium perchlorate 、 丙酮 在 三乙胺 作用下， 反应 0.5h， 以62%的产率得到7'-(dimethylamino)-4,4-dimethyl-2'-phenylspiro[3H-pyrano[3,2-c]chromene-2,4'-chromene]-5-one
  参考文献：
  名称：

  Synthesis and Characterization of Coumarin-Based Spiropyran Photochromic Colorants

  摘要：

  Two coumarin-based spiropyran derivatives were synthesized and characterized in two steps to explore their photochromic properties. Both prepared compounds are sensitive to UV light and change colors upon irradiation. The resulting photogenerated zwitterions revert to the original compounds while being heated. A new family of organic photochromic colorants is introduced.

  DOI：

  10.1021/ol8018902

文献信息

• PHOTOCHROMIC DETECTION OF ULTRAVIOLET IRRADIATION
  申请人：PurpleSun Inc.

  公开号：US20150343102A1

  公开（公告）日：2015-12-03

  The present invention provides methods for detecting electromagnetic energy (e.g., ultraviolet radiation) and articles suitable for use in such methods. The methods and articles can be useful for detecting sterilization or disinfection resulting from electromagnetic energy such as ultraviolet C. Detection of the sterilization or disinfection allows discontinuation of the exposure when a desired level of sterilization or disinfection has been obtained. Feedback mechanisms for controlling exposure to the energy may also be used.