m-Nitro-cumyl-(α)-chlorid | 21078-59-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: m-Nitro-cumyl-(α)-chlorid
• 英文别名: 1-(2-Chloropropan-2-yl)-3-nitrobenzene；1-(2-chloropropan-2-yl)-3-nitrobenzene
• CAS: 21078-59-1
• 化学式: C₉H₁₀ClNO₂
• 分子量: 199.637
• InChiKey: QMYCGOZNOOTDLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  45.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  m-Nitro-cumyl-(α)-chlorid 在 六甲基磷酰三胺 、 sodium azide 作用下， 生成 对硝基叠氮化物
  参考文献：
  名称：

  New and facile substitution reactions at tertiary carbon. The use of oxygen as a mechanistic probe

  摘要：

  DOI：

  10.1021/ja01024a053
• 作为产物：
  描述：

  间异丙基硝基苯 在 盐酸 、 四氯化碳 、 N-溴代丁二酰亚胺(NBS) 、 三氯化铁 、 过氧化苯甲酰 作用下， 生成 m-Nitro-cumyl-(α)-chlorid
  参考文献：
  名称：

  A Spiral Curriuculm for Hypnosis Training

  摘要：

  Although hypnosis has been used for centuries, there are few reports of systematic, professional training. The most thorough codification of instructional content is the Standards of Training in Clinical Hypnosis (SOTCH) (Elkins & Hammond, 1994), endorsed by The American Society of Clinical Hypnosis (ASCH), and The Society of Clinical and Experimental Hypnosis (SCEH) for annual workshops. This curriculum is organized around two assumptions: training is presented to adult professionals who know their own objectives; and each participant has a favorite leaming style that should be accommodated. The workshop follows the content and time recommendations of the SOTCH. Some content is scheduled with spaced opportunity for practice. Concepts are organized in a spiral pattern, then presented and reviewed several times, each time in more detail, and in ways that accommodate different learning styles.

  DOI：

  10.1080/00029157.2002.10403509

文献信息

• How do reaction mechanisms change? Appearance of concerted pericyclic elimination for the reaction of cumyl derivatives
  作者：Tina L. Amyes、John P. Richard

  DOI：10.1021/ja00023a062

  日期：1991.11
• New and facile substitution reactions at tertiary carbon. The use of oxygen as a mechanistic probe
  作者：Nathan Kornblum、Gary W. Earl、Norman L. Holy、Joseph W. Manthey、Michael T. Musser、Donald H. Snow、R. Thomas Swiger

  DOI：10.1021/ja01024a053

  日期：1968.10
• A Spiral Curriuculm for Hypnosis Training
  作者：David M. Wark、Daniel P. Kohen

  DOI：10.1080/00029157.2002.10403509

  日期：2002.10

  Although hypnosis has been used for centuries, there are few reports of systematic, professional training. The most thorough codification of instructional content is the Standards of Training in Clinical Hypnosis (SOTCH) (Elkins & Hammond, 1994), endorsed by The American Society of Clinical Hypnosis (ASCH), and The Society of Clinical and Experimental Hypnosis (SCEH) for annual workshops. This curriculum is organized around two assumptions: training is presented to adult professionals who know their own objectives; and each participant has a favorite leaming style that should be accommodated. The workshop follows the content and time recommendations of the SOTCH. Some content is scheduled with spaced opportunity for practice. Concepts are organized in a spiral pattern, then presented and reviewed several times, each time in more detail, and in ways that accommodate different learning styles.
• New and facile substitution reactions at tertiary carbon. The m-nitrocumyl system
  作者：Nathan Kornblum、Thomas M. Davies、Gary W. Earl、Norman L. Holy、Joseph W. Manthey、Michael T. Musser、R. Thomas Swiger

  DOI：10.1021/ja01024a052

  日期：1968.10