acetic acid-(1-allyl-1-methyl-but-3-enyl ester) | 88974-44-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: acetic acid-(1-allyl-1-methyl-but-3-enyl ester)
• 英文别名: Essigsaeure-(1-allyl-1-methyl-but-3-enylester)；4-Methylhepta-1,6-dien-4-yl acetate
• CAS: 88974-44-1
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: VRIXCHDBBSDNEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  acetic acid-(1-allyl-1-methyl-but-3-enyl ester) 在 polystyrene supported alkylideneruthenium 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 以95%的产率得到1-methyl-3-cyclopenten-1-yl acetate
  参考文献：
  名称：

  Olefin metathesis in non-degassed solvent using a recyclable, polymer supported alkylideneruthenium

  摘要：

  聚苯乙烯支撑的钌络合物 8 是一种用于烯烃偏析反应的强效原催化剂，可用于非脱气溶剂，并且无需添加稳定剂即可循环使用。

  DOI：

  10.1039/b007304k
• 作为产物：
  描述：

  乙酰溴 、 di-n-butylallyltin isothiocyanate 反应 3.0h， 以70%的产率得到acetic acid-(1-allyl-1-methyl-but-3-enyl ester)
  参考文献：
  名称：

  Allylchlorotins as allylating agents of acyl chlorides

  摘要：

  DOI：

  10.1016/s0022-328x(00)99274-x

文献信息

• A recyclable ‘boomerang’ polymer-supported ruthenium catalyst for olefin metathesis
  作者：Mahmood Ahmed、Anthony G.M. Barrett、D.Christopher Braddock、Susan M. Cramp、Panayiotis A. Procopiou

  DOI：10.1016/s0040-4039(99)01833-x

  日期：1999.12

  Polymer supported ruthenium catalyst 8 was found to be an effective catalyst for ring closing metathesis. The rate of reaction and activity was found to be comparable to that of homogeneous catalyst 1. In addition, the catalyst could be recycled and re-used up to three times by simple filtration. The residual ruthenium/catalyst content in the product mixtures using catalyst 8 were found to be much reduced

  发现聚合物负载的钌催化剂8是用于闭环复分解的有效催化剂。发现反应速率和活性与均相催化剂1相当。另外，该催化剂可通过简单过滤而再循环并重复使用多达三遍。发现与均相催化剂1相比，使用催化剂8的产物混合物中的残余钌/催化剂含量大大降低。
• Yano, Katsunori; Baba, Akio; Matsuda, Haruo, Chemistry Letters, 1991, p. 1181 - 1184
  作者：Yano, Katsunori、Baba, Akio、Matsuda, Haruo

  DOI：——

  日期：——
• Cyclization/Hydrosilylation of Functionalized Dienes Catalyzed by a Cationic Palladium Phenanthroline Complex
  作者：Ross A. Widenhoefer、Carmine N. Stengone

  DOI：10.1021/jo9913006

  日期：1999.11.1

  Mixtures of(phen)PdMe2 (2a) and HBAr'(4) (3a) or (phen)PdMe(Cl) (2b) and NaBAr'(4) (3b) [phen = 1, 10-phenanthroline; Ar' = 3,5-C6H3(CF3)(2)] catalyzed the cyclization/hydrosilylation of functionalized 1,6-dienes to form silylated cyclopentanes in good yield and with excellent trans selectivity about the newly formed C-C bond (typically >50:1). A range of tertiary hydrosilanes were employed in the procedure although unhindered trialkylsilanes provided the most consistent results. The protocol tolerated a range of polar functionality including esters, ethers, amides, sulfones, and cyano groups. 4,4-Disubstitution on the diene backbone promoted cyclization, and a homoallylic ester, ketone, or ether directing group was required for efficient cyclization. The procedure tolerated dienes which possessed a single trans-substituted olefin and also tolerated allylic substitution. These substituted dienes underwent cyclization/hydrosilylation to form carbocycles resulting from transfer of the silyl group to the less hindered olefin. Mixtures of 2a and 3a also catalyzed the cyclization/hydrosilylation of functionalized 1,7-dienes to form silylated cyclohexane derivatives. Cyclization/hydrosilylation of 1,7-dienes was typically slower, less stereoselective, and more sensitive to substitution than was cyclization of 1,6-dienes.
• GAMBARO, A.;PERUZZO, V.;MARTON, D., J. ORGANOMET. CHEM., 1983, 258, N 3, 291-296
  作者：GAMBARO, A.、PERUZZO, V.、MARTON, D.

  DOI：——

  日期：——
• Diallylmethylcarbinyl Acetate
  作者：William G. Young、Lawrence J. Andrews、Stanley J. Cristol

  DOI：10.1021/ja01248a507

  日期：1943.8