7-Tetrahydro<2>furyl-heptan-1-ol | 3214-33-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 7-Tetrahydro<2>furyl-heptan-1-ol
• 英文别名: 7-(Oxolan-2-yl)heptan-1-ol
• CAS: 3214-33-3
• 化学式: C₁₁H₂₂O₂
• 分子量: 186.294
• InChiKey: DGUIVGMCWWYMBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 7-(tert-butylperoxy)hept-1-ene 反应 10.0h， 以20%的产率得到7-Tetrahydro<2>furyl-heptan-1-ol
  参考文献：
  名称：

  置换同分子内分子。12-分解过氧乙烯

  摘要：

  过氧化物CH 2＝ CH-（CH 2）n OOtBu ，（n ＝ 1-5）的热解的产物分析表明，在n ＝1、2、3、4时发生了诱导的分解。THF，四氯化碳，溴三氯甲烷的自由基加成已在较低温度下进行；他们通过分离过氧化物加合物，至少在每种情况下对一种过氧化物进行了分离，证明了两步机理（自由基Z·加到双键上，分子内均质置换）参与了诱导的三价氧的分解。。可以估计这些S H i反应的速率常数的数量级。

  DOI：

  10.1016/s0040-4020(01)82080-9

文献信息

• SUPPORTED NON-METALLOCENE OLEFIN POLYMERIZATION CATALYST, AND PREPARATION AND USE THEREOF
  申请人：Yangzi Petrochemical Company Co., Ltd.

  公开号：EP1829897B1

  公开（公告）日：2014-12-10
• Supported Nonmetallocene Olefin Polymerization Catalyst, Preparation Method and Use Thereof
  申请人：Dai Houliang

  公开号：US20080227936A1

  公开（公告）日：2008-09-18

  The present invention provides a method for supporting a nonmetallocene olefin polymerization catalyst, comprising the following steps: a carrier reacts with a chemical activator to obtain a modified carrier; a magnesium compound is dissolved in a tetrahydrofuran-alcohol mixed solvent to form a solution, then the modified carrier is added to the solution to perform a reaction, then filtered and washed, dried and suction dried to prepare a composite carrier; a nonmetallocene olefin polymerization catalyst is dissolved in a solvent, and then reacts with said composite carrier, then is washed and filtered, dried and suction dried, to prepare a supported nonmetallocene olefin polymerization catalyst. The present invention further relates to a supported nonmetallocene olefin polymerization catalyst as prepared by this method. The present invention further relates to the use of the supported nonmetallocene olefin polymerization catalyst in an olefin polymerization and an olefin copolymerization between two or more different olefins. In one specific embodiment, the present invention relates to the use of the supported nonmetallocene olefin polymerization catalyst in a slurry ethylene polymerization. The present invention provides a new type of catalyst that improves the polymer morphology, increases polymer bulk density and enhances polymerization activity.
• US7875568B2
  申请人：——

  公开号：US7875568B2

  公开（公告）日：2011-01-25
• Deplacements homolytiques intramoleculaires. 12-decomposition induite de peroxydes ethyleniques : influence de la longueur de la chaine
  作者：M.J. Bourgeois、B. Maillard、E. Montaudon

  DOI：10.1016/s0040-4020(01)82080-9

  日期：1986.1

  Products analyses of the thermolyses of the peroxides CH2=CH-(CH2)n OOtBu, , (n= 1-5) showed that an induced decomposition of occured for n=l,2,3,4. Free radical additions of THF, carbon tetrachloride, bromotrichloromethane to have been performed at lower temperature ; they allowed, through the isolation of an adduct peroxide, at least in one case for each peroxide, to prove that a two-steps mechanism

  过氧化物CH 2＝ CH-（CH 2）n OOtBu ，（n ＝ 1-5）的热解的产物分析表明，在n ＝1、2、3、4时发生了诱导的分解。THF，四氯化碳，溴三氯甲烷的自由基加成已在较低温度下进行；他们通过分离过氧化物加合物，至少在每种情况下对一种过氧化物进行了分离，证明了两步机理（自由基Z·加到双键上，分子内均质置换）参与了诱导的三价氧的分解。。可以估计这些S H i反应的速率常数的数量级。