(+/-)-1-Methyl-1,2,3,4-tetrahydrocyclopentindole | 114218-66-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (+/-)-1-Methyl-1,2,3,4-tetrahydrocyclopentindole
• 英文别名: 1-Methyl-1,2,3,4-tetrahydrocyclopenta[b]indole
• CAS: 114218-66-5
• 化学式: C₁₂H₁₃N
• 分子量: 171.242
• InChiKey: QUYRJDMUKFGIAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (+/-)-3-Methylcyclopentanone Phenylhydrazone 以 乙二醇 为溶剂， 反应 5.0h， 生成 (+/-)-1-Methyl-1,2,3,4-tetrahydrocyclopentindole 、 (+/-)-2-Methyl-1,2,3,4-tetrahydrocyclopentindole
  参考文献：
  名称：

  Robinson, Brian, Journal of Heterocyclic Chemistry, 1987, vol. 24, p. 1321 - 1323

  摘要：

  DOI：

文献信息

• Novel indoline dye tetrabutylammonium carboxylates attached with a methyl group on the cyclopentane ring for dye-sensitized solar cells
  作者：Masaki Matsui、Yuya Tsuzuki、Yasuhiro Kubota、Kazumasa Funabiki、Toshiyasu Inuzuka、Kazuhiro Manseki、Shinji Higashijima、Hidetoshi Miura、Hiroyasu Sato、Tsukasa Yoshida

  DOI：10.1016/j.tet.2018.08.006

  日期：2018.10

  (2R,3aR,8bR)- and (2S,3aS,8bS)-2-Methyl indoline dye tetrabutylammonium carboxylates exhibited the highest conversion efficiency among four regio and stereo isomers. These indoline dyes also showed higher conversion efficiency than DN350.

  （2 R，3a R，8b R）-和（2 S，3a S，8b S）-2-甲基吲哚染料四丁基铵羧酸盐在四种区域和立体异构体中表现出最高的转化效率。这些吲哚染料的转化率也比DN350高。
• Synthesis of Indoles from <i>o</i>-Haloanilines
  作者：Assia Chebieb、Young Gyu Kim、Jin Kun Cha

  DOI：10.1021/acs.joc.3c01047

  日期：2023.7.21

  A convenient method for the synthesis of indoles has been developed by the sequential orchestration of the cross-coupling reaction of o-haloaniline and PIFA oxidation of the resulting 2-alkenylanilines. A highlight of this two-step indole synthesis is a modular strategy which is applicable to both acyclic and cyclic starting materials. Particularly noteworthy is the regiochemistry that is complementary

  通过邻卤代苯胺的交叉偶联反应和所得 2-烯基苯胺的 PIFA 氧化的顺序协调，开发了一种合成吲哚的简便方法。这种两步吲哚合成的一个亮点是适用于无环和环状起始材料的模块化策略。特别值得注意的是与费歇尔吲哚合成和相关变体互补的区域化学。直接制备没有N-保护基团的N -H吲哚也是有利的。
• DEUTERATED HETEROCYCLIC COMPOUND, ORGANIC LIGHT EMITTING DEVICE INCLUDING THE SAME AND COMPOSITION FOR ORGANIC LAYER OF ORGANIC LIGHT EMITTING DEVICE
  申请人：LG Display Co., Ltd.

  公开号：EP4074706A1

  公开（公告）日：2022-10-19

  The present disclosure relates to a deuterated heterocyclic compound being represented by following Formula, an organic light emitting device including the heterocyclic compound and an organic light emitting display device including the organic light emitting device. The heterocyclic compound is included in an organic material layer of the organic light emitting device.

  本公开涉及一种用下式表示的氚代杂环化合物、一种包括该杂环化合物的有机发光器件和一种包括该有机发光器件的有机发光显示装置。杂环化合物包含在有机发光器件的有机材料层中。
• ROBINSON, BRIAN, J. HETEROCYCL. CHEM., 24,(1987) N 5, 1321-1323
  作者：ROBINSON, BRIAN

  DOI：——

  日期：——
• Robinson, Brian, Journal of Heterocyclic Chemistry, 1987, vol. 24, p. 1321 - 1323
  作者：Robinson, Brian

  DOI：——

  日期：——