1-Butoxy-4-(diethoxyphosphorylmethyl)benzene | 198819-50-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1-Butoxy-4-(diethoxyphosphorylmethyl)benzene
• CAS: 198819-50-0
• 化学式: C₁₅H₂₅O₄P
• 分子量: 300.335
• InChiKey: TWTDPDWLKFBOHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  20
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-Butoxy-4-(diethoxyphosphorylmethyl)benzene 在 正丁基锂 、 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 生成 1-[5-((E)-4-butoxystyryl)-2-thienyl]-2-[5-((E)-4-nitrostyryl)-2-thienyl]ethene
  参考文献：
  名称：

  Synthesis and characterization of end-functionalized oligo(vinylthiophenes) with liquid crystal properties

  摘要：

  A general scheme for the synthesis of end-functionalized conjugated (E)-vinylthiophene oligomers with liquid crystal and potential second-order non-linear optical properties is described, These push-pull thiophene-containing aromatic molecules show mesogenic properties over different temperature ranges depending on the chain length and the functional end-groups.

  DOI：

  10.1039/p29960000713
• 作为产物：
  描述：

  4-丁氧基苯甲醇 在 盐酸 作用下， 生成 1-Butoxy-4-(diethoxyphosphorylmethyl)benzene
  参考文献：
  名称：

  Synthesis and characterization of end-functionalized oligo(vinylthiophenes) with liquid crystal properties

  摘要：

  A general scheme for the synthesis of end-functionalized conjugated (E)-vinylthiophene oligomers with liquid crystal and potential second-order non-linear optical properties is described, These push-pull thiophene-containing aromatic molecules show mesogenic properties over different temperature ranges depending on the chain length and the functional end-groups.

  DOI：

  10.1039/p29960000713

文献信息

• Synthesis and characterization of end-functionalized oligo(vinylthiophenes) with liquid crystal properties
  作者：Christophe Maertens、Jian-Xin Zhang、Philippe Dubois、Robert Jérôme

  DOI：10.1039/p29960000713

  日期：——

  A general scheme for the synthesis of end-functionalized conjugated (E)-vinylthiophene oligomers with liquid crystal and potential second-order non-linear optical properties is described, These push-pull thiophene-containing aromatic molecules show mesogenic properties over different temperature ranges depending on the chain length and the functional end-groups.