申请人:Yoo Keun-Hoon
公开号:US20050107540A1
公开(公告)日:2005-05-19
The present invention relates to a process for preparing thermoplastic resin for extrusion sheets, and particularly to a process for preparing acrylonitrile-butadiene-styrene (ABS) thermoplastic transparent resin for extrusion sheets having superior impact resistance, chemical resistance, processability, whitening resistance, high temperature elongation, etc. and very superior transparency, by controlling a mixing ratio of a methacrylate alkylester compound or acrylate alkylester compound, an aromatic vinyl compound, and a vinylcyanide compound grafted on conjugated diene rubber latex of which an average particle diameter and gel contents (degree of crosslinking) are optimized to control a refractive index of the monomer mixture to be similar to that of the rubber latex, and optimizing the molecular weight.
本发明涉及一种挤出片材用热塑性树脂的制备工艺,特别是涉及一种挤出片材用丙烯腈-丁二烯-苯乙烯(ABS)热塑性透明树脂的制备工艺,该树脂具有优异的抗冲击性、耐化学性、加工性、耐白化性、高温伸长率等。该技术通过控制接枝在共轭二烯橡胶胶乳上的甲基丙烯酸酯烷基酯化合物或丙烯酸酯烷基酯化合物、芳香族乙烯基化合物和乙烯基氰化物化合物的混合比例,优化其平均粒径和凝胶含量(交联度),以控制单体混合物的折射率与橡胶胶乳的折射率相似,并优化分子量。