(2-Nitro-phenyl)-trimethylsilanyl-amine | 136412-76-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-Nitro-phenyl)-trimethylsilanyl-amine
• 英文别名: N-trimethylsilyl-o-nitroaniline；2-nitro-N-trimethylsilylaniline
• CAS: 136412-76-5
• 化学式: C₉H₁₄N₂O₂Si
• 分子量: 210.308
• InChiKey: TXPBUKNAUQXTKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.84
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  57.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (2-Nitro-phenyl)-trimethylsilanyl-amine 、 叔丁胺 在 乙基溴化镁 作用下， 生成 1-amino-2-(tert-butylazoxy)benzene
  参考文献：
  名称：

  Synthesis of 1-tert-butyl-2-aryldiazene-2-oxides by reactions of t-BuNHMgBr with nitrobenzenes

  摘要：

  A new method has been developed for the synthesis of alkylaryldiazene oxides by the reactions of t-BuNHMgBr with nitrobenzenes. The cis-azoxy compound 1-tert-butyl-2-(2-chlorophenyl)diazene-2-oxide, which irreversibly isomerizes to the trans isomer upon heating, was obtained for the first time under chemical reaction conditions.

  DOI：

  10.1007/bf00961304
• 作为产物：
  描述：

  三甲基氯硅烷 、 2-硝基苯胺 在 三乙胺 作用下， 以 苯 为溶剂， 反应 6.0h， 以87%的产率得到(2-Nitro-phenyl)-trimethylsilanyl-amine
  参考文献：
  名称：

  Synthesis of 1-tert-butyl-2-aryldiazene-2-oxides by reactions of t-BuNHMgBr with nitrobenzenes

  摘要：

  A new method has been developed for the synthesis of alkylaryldiazene oxides by the reactions of t-BuNHMgBr with nitrobenzenes. The cis-azoxy compound 1-tert-butyl-2-(2-chlorophenyl)diazene-2-oxide, which irreversibly isomerizes to the trans isomer upon heating, was obtained for the first time under chemical reaction conditions.

  DOI：

  10.1007/bf00961304

文献信息

• Synthesis of 1-tert-butyl-2-aryldiazene-2-oxides by reactions of t-BuNHMgBr with nitrobenzenes
  作者：�. T. Apasov、B. A. Dzhetigenov、Yu. A. Strelenko、A. V. Kalinin、V. A. Tartakovskii

  DOI：10.1007/bf00961304

  日期：1991.6

  A new method has been developed for the synthesis of alkylaryldiazene oxides by the reactions of t-BuNHMgBr with nitrobenzenes. The cis-azoxy compound 1-tert-butyl-2-(2-chlorophenyl)diazene-2-oxide, which irreversibly isomerizes to the trans isomer upon heating, was obtained for the first time under chemical reaction conditions.