(2E)-1,3,3-trimethyl-2-[2-[2-phenylsulfanyl-3-[2-(1,3,3-trimethylindol-1-ium-2-yl)ethenyl]cyclohex-2-en-1-ylidene]ethylidene]indole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: (2E)-1,3,3-trimethyl-2-[2-[2-phenylsulfanyl-3-[2-(1,3,3-trimethylindol-1-ium-2-yl)ethenyl]cyclohex-2-en-1-ylidene]ethylidene]indole
• 化学式: C38H41N2S+
• 分子量: 557.8
• InChiKey: FWCJTOOQIVQKBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  41
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  31.6
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• NEAR-INFRARED ABSORBING DYE, NEAR-INFRARED ABSORPTIVE FILM-FORMING COMPOSITION, AND NEAR-INFRARED ABSORPTIVE FILM
  申请人：OHASHI Masaki

  公开号：US20120119171A1

  公开（公告）日：2012-05-17

  A near-infrared absorbing dye has an anion of formula (1) wherein A 1 is H or CF 3 , R 0 is OH or —OC(═O)—R′, and R′ is a monovalent hydrocarbon group. The dye has excellent solvent solubility as well as good optical properties and heat resistance, offering the advantages of easy coating and effective working during film formation. The dye free of heavy metal in its structure is advantageously used in the process of fabricating semiconductor devices.

  一种近红外吸收染料具有如下式（1）的阴离子，其中A1为H或CF3，R0为OH或—OC(═O)—R′，而R′为一价碳氢基团。该染料具有优异的溶剂溶解性以及良好的光学性能和耐热性，提供易于涂覆和在薄膜形成过程中有效工作的优点。该染料在其结构中不含重金属，因此在制造半导体器件的过程中具有优势应用。
• [EN] INFRARED ABSORBING COMPOUNDS AND THEIR USE IN IMAGEABLE ELEMENTS<br/>[FR] COMPOSES ABSORBEURS D'UV ET LEUR UTILISATION DANS DES ELEMENTS IMAGEABLES
  申请人：KODAK POLYCHROME GRAPHICS LLC

  公开号：WO2004069938A1

  公开（公告）日：2004-08-19

  Infrared absorbing compounds in which both the anion and the cation absorb infrared radiation, imageable elements that contain these compounds, and methods for forming images using the imageable elements are disclosed. The compounds have the structure (I) and (II) in which Y1 and Y2 are each independently hydrogen, halo, alkyl, diphenylamino, or phenylthio; R1, R2, R3 and R4 are each independently hydrogen, methyl, or SO3-, with the proviso that two fo R1, R2, R3, and R4 are SO3-; R5 and R6 are each independently an alkyl group; Z1, Z2, Z4 and Z5 are each independently a benzo group or a nophtho group; Z3 and Z6 are each independently two hydrogen atoms, a cyclohexene residue, or a cyclopentene residue; X1, X2, X3, and X4 are each independently S, O, NH, CH2, or C(CH3)2; and n1 and n2 are each independently 0 to 4.

  本发明涉及吸收红外辐射的化合物，其中阴离子和阳离子均吸收红外辐射，包含这些化合物的可成像元素以及使用可成像元素形成图像的方法。化合物具有结构（I）和（II），其中Y1和Y2分别独立地为氢、卤素、烷基、二苯胺或苯硫醚；R1、R2、R3和R4分别独立地为氢、甲基或SO3-，但其中两个为SO3-；R5和R6分别独立地为烷基；Z1、Z2、Z4和Z5分别独立地为苯并环或萘并环；Z3和Z6分别独立地为两个氢原子、环己烯残基或环戊烯残基；X1、X2、X3和X4分别独立地为S、O、NH、CH2或C（CH3）2；n1和n2分别独立地为0至4。
• Process for the preparation of cyanine dyes with polysulfonate anions
  申请人：Tao Ting

  公开号：US20050113546A1

  公开（公告）日：2005-05-26

  A convenient and economical method for preparing infrared absorbing cyanine dyes useful in lithographic printing plate precursors is disclosed. The reaction is generally carried out by condensation of a heterocyclic base containing an activated methylene group and an unsaturated bisaldehyde or its equivalent in a solvent or solvent mixture at about 20-150° C. All the reactions necessary for production of the infrared absorbing cyanine dye may be carried out in one reaction vessel without isolating any intermediate products.

  本发明公开了一种制备适用于制作印刷版前体的红外吸收青光菁染料的方便经济方法。通常通过在溶剂或溶剂混合物中，在大约20-150℃的条件下，将含有活性亚甲基基团和不饱和双醛或其等效物的杂环碱缩合反应来完成。制备红外吸收青光菁染料所需的所有反应都可以在一个反应容器中完成，而无需分离任何中间产物。
• Infra red absorbing compounds and their use in photoimageable elements
  申请人：——

  公开号：US20040180285A1

  公开（公告）日：2004-09-16

  Infrared absorbing compounds in which the anion is selected from the group consisting of 5-isatinsulfonate, 10-camphorsulfonate, and 4,5-dihydroxy-1,3-benzenedisulfonate are disclosed. Negative-working imageable elements containing these compounds have improved dot stability.

  本发明揭示了阴离子选自5-异吲哚磺酸盐、10-樟脑磺酸盐和4,5-二羟基-1,3-苯二磺酸盐等组成的红外吸收化合物。包含这些化合物的负向感光元件具有改善的点稳定性。
• CYANOBORATE, FLUOROALKYLPHOSPHATE, FLUOROALKYLBORATE OR IMIDE DYES
  申请人：IGNATYEV Nikolai (Mykola)

  公开号：US20110190480A1

  公开（公告）日：2011-08-04

  The present invention relates to dyes of the general formula CAT + Y − (I), where Y − is an anion selected from the group of the cyanoborates, fluoroalkylphosphates, fluoroalkylborates or imidates and CAT + is a cation selected from the group of the azine, xanthene, polymethine, styryl, azo, tetrazolium, pyrylium, benzopyrylium, thiopyrylium, benzothiopyrylium, thiazine, oxazine, triarylmethane, diarylmethane, methine, acridine, quinoline, isoquinoline or quaternary azafluorenone dyes, for colouring plastics and plastic fibres, for the preparation of flexographic printing inks, as ball-point pen pastes, as stamp ink, for colouring leather and paper, for use in data acquisition systems, reprography, in ink microfilters, in photogalvanics, laser technology and the photo industry.

  本发明涉及一般式CAT+Y−（I）的染料，其中Y−是从氰硼酸盐、氟烷基磷酸盐、氟烷基硼酸盐或咪唑盐群中选择的阴离子，CAT+是从偶氮、黄色素、聚甲烯、苯乙烯、偶氮、四唑、吡啶、苯并吡喃、硫吡喃、苯并硫吡喃、噻吩、噁唑、三芳基甲烷、二芳基甲烷、甲烷、吖啶、喹啉、异喹啉或季铵氮芴酮染料群中选择的阳离子，用于着色塑料和塑料纤维，制备柔性版印刷油墨，作为圆珠笔膏、邮票墨水，用于着色皮革和纸张，用于数据采集系统，复印术，墨水微滤器，光电镀技术，激光技术和光学工业。