Anilinoprop-1-enyl-(triphenyl)-phosphonium Bromide | 54774-75-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Anilinoprop-1-enyl-(triphenyl)-phosphonium Bromide
• 英文别名: 2-(N-phenylamino)-vinyltriphenylphosphonium bromide；[(E)-2-anilinoprop-1-enyl]-triphenylphosphanium;bromide
• CAS: 54774-75-3
• 化学式: Br*C₂₇H₂₅NP
• 分子量: 474.38
• InChiKey: DJZUTJFXVHWYCR-PGCQSHBKSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.96
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  炔丙基三苯基溴化膦 、 四苯基氨化膦 以 二氯甲烷 为溶剂， 反应 40.0h， 生成 Anilinoprop-1-enyl-(triphenyl)-phosphonium Bromide
  参考文献：
  名称：

  Barluenga, Jose; Merino, Isabel; Palacios, Francisco, Journal of the Chemical Society. Perkin transactions I, 1991, # 2, p. 341 - 345

  摘要：

  DOI：

文献信息

• LIGANDS FOR METALS AS CATALYSTS FOR CARBON-CARBON BOND FORMATION
  申请人：LIANG Lan-Chang

  公开号：US20090163740A1

  公开（公告）日：2009-06-25

  The present invention provides a family of novel and stable ligands which chelate with a metal to form a complex. The ligand contains a t-butyl group or a ring, particularly a substituted aromatic group, linked to a nitrogen atom. The nitrogen atom further links to PR 1 R 2 , PR 1 R 2 R 9 , P(═O)R 1 R 2 , NR 1 R 2 , OR 1 , SR 1 , or AsR 1 R 2 group with a saturated or unsaturated hydrocarbon such that the structure of the ligand can be stabilized.

  本发明提供了一系列新颖且稳定的配体，这些配体与金属螯合形成复合物。该配体含有t-丁基基团或环，特别是取代芳基团，与氮原子连接。氮原子进一步与PR1R2、PR1R2R9、P(═O)R1R2、NR1R2、OR1、SR1或AsR1R2基团链接，带有饱和或不饱和的碳氢化合物，从而使配体的结构得以稳定。
• β-Aminovinylphosphonium Salts—A Novel Synthesis, Properties, and Structure
  作者：Roman Mazurkiewicz、Beata Fryczkowska、Rafał Gabański、Mirosława Grymel、Justyna Libera

  DOI：10.1080/10426500701642971

  日期：2008.5.14

  The deacylation of easily accessible -(N-acylamino)vinylphosphonium salts with methanol or some other nucleophiles gives -aminovinylphosphonium salts in good yields. As indicated by the spectroscopic properties and by the results of single crystal X-ray diffraction studies the N-alkyl derivatives of the investigated compounds should be considered as strongly resonance stabilized -iminium ylides rather than -aminovinylphosphonium salts. In the case of N-aryl derivatives, the -iminium ylide resonance structures are probably less pronounced.
• Barluenga, Jose; Merino, Isabel; Palacios, Francisco, Journal of the Chemical Society. Perkin transactions I, 1991, # 2, p. 341 - 345
  作者：Barluenga, Jose、Merino, Isabel、Palacios, Francisco

  DOI：——

  日期：——