9,10-bis(2-naphthylthio)anthracene | 1260115-38-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-bis(2-naphthylthio)anthracene
• 英文别名: ANS；9,10-Bis(naphthalen-2-ylsulfanyl)anthracene；9,10-bis(naphthalen-2-ylsulfanyl)anthracene
• CAS: 1260115-38-5
• 化学式: C₃₄H₂₂S₂
• 分子量: 494.681
• InChiKey: GQYYNJXDVCLWFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  36
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  9,10-蒽二乙酸酯 、 2-萘硫醇 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以17%的产率得到9,10-bis(2-naphthylthio)anthracene
  参考文献：
  名称：

  Organic electroluminescence devices based on anthracene sulfide derivatives

  摘要：

  A series of anthracene derivatives are synthesized and fabricated as light-emitting materials in OLED devices. The incorporation of the chalcogen atoms, either oxygen or sulfur, in between the anthracene moiety and the alkyl or aryl substituents affected drastically the photo- and electroluminescence properties of the materials, especially the HOMO-LUMO band gap and the emitting color of the devices. The new anthracene sulfide derivatives represent a new design for further modification of other light-emitting doped materials. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.09.089

文献信息

• Organic electroluminescence devices based on anthracene sulfide derivatives
  作者：Chakkrapan Nerungsi、Piangkhwan Wanitchang、Somboon Sahasithiwat、Karoon Sadorn、Teerakiat Kerdcharoen、Tienthong Thongpanchang

  DOI：10.1016/j.tetlet.2010.09.089

  日期：2010.12

  A series of anthracene derivatives are synthesized and fabricated as light-emitting materials in OLED devices. The incorporation of the chalcogen atoms, either oxygen or sulfur, in between the anthracene moiety and the alkyl or aryl substituents affected drastically the photo- and electroluminescence properties of the materials, especially the HOMO-LUMO band gap and the emitting color of the devices. The new anthracene sulfide derivatives represent a new design for further modification of other light-emitting doped materials. (C) 2010 Elsevier Ltd. All rights reserved.