10-[[2,5-Dimethoxy-4-(phenothiazin-10-ylmethyl)phenyl]methyl]phenothiazine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 10-[[2,5-Dimethoxy-4-(phenothiazin-10-ylmethyl)phenyl]methyl]phenothiazine
• 化学式: C₃₄H₂₈N₂O₂S₂
• 分子量: 560.741
• InChiKey: DLYGLHSTUPUHEX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  75.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  10-[[2,5-Dimethoxy-4-(phenothiazin-10-ylmethyl)phenyl]methyl]phenothiazine 在 吡啶 、 四氯化钛 、 锌 、 三氯氧磷 作用下， 以 四氢呋喃 、 1,2-二氯乙烷 为溶剂， 反应 48.0h， 生成 33,67,69,73-tetramethoxy-10,23,44,57-tetrathia-3,30,37,64-tetrazapentadecacyclo[64.2.2.232,35.111,15.118,22.145,49.152,56.03,12.04,9.021,30.024,29.037,46.038,43.055,64.058,63]hexaheptaconta-1(68),4,6,8,11,13,15(76),16,18(75),19,21,24,26,28,32(74),33,35(73),38,40,42,45,47,49(72),50,52(71),53,55,58,60,62,66,69-dotriacontaene
  参考文献：
  名称：

  Synthesis and Antimicrobicidal Activity of Phenothiazinophanes: A New Class of Permanent Fluorescence Sensing Stilbenophanes

  摘要：

  描述了苯噻嗪芳烃和手性苯噻嗪芳烃的合成、表征及抗微生物活性。合成的化合物还表现出优异的荧光传感特性。

  DOI：

  10.14233/ajchem.2015.19128
• 作为产物：
  描述：

  吩噻嗪 、 1,4-二(溴甲基)-2,5-二甲氧基苯 在 sodium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 反应 48.0h， 以78%的产率得到10-[[2,5-Dimethoxy-4-(phenothiazin-10-ylmethyl)phenyl]methyl]phenothiazine
  参考文献：
  名称：

  Synthesis and optoelectrochemical properties of novel phenothiazinophanes

  摘要：

  Phenothiazinophanes, a novel class of phenothiazine based stilbenophanes are synthesized and characterized. All the phenothiazinophanes exhibited excellent photoluminescence properties. The cyclic voltammetry studies of the phenothiazinophanes demonstrated multiple absorption peaks due to the formation of radical cations (polarons) and dications (bipolarons). (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2007.09.161

文献信息

• Synthesis and optoelectrochemical properties of novel phenothiazinophanes
  作者：Perumal Rajakumar、Rajagopal Kanagalatha

  DOI：10.1016/j.tetlet.2007.09.161

  日期：2007.11

  Phenothiazinophanes, a novel class of phenothiazine based stilbenophanes are synthesized and characterized. All the phenothiazinophanes exhibited excellent photoluminescence properties. The cyclic voltammetry studies of the phenothiazinophanes demonstrated multiple absorption peaks due to the formation of radical cations (polarons) and dications (bipolarons). (c) 2007 Elsevier Ltd. All rights reserved.
• Synthesis and Antimicrobicidal Activity of Phenothiazinophanes: A New Class of Permanent Fluorescence Sensing Stilbenophanes
  作者：Rajagopal Kanagalatha、Perumal Rajakumar、C.S. Senthamil Selvi、Natarajan Mohan

  DOI：10.14233/ajchem.2015.19128

  日期：——

  The synthesis, characterization and antimicrobicidal activity of phenophiazinophane and chiral phenothiazinophanes are described. The synthesized compounds also exhibits excellent fluorescent sensing properties.

  描述了苯噻嗪芳烃和手性苯噻嗪芳烃的合成、表征及抗微生物活性。合成的化合物还表现出优异的荧光传感特性。