1-(9H-carbazol-1-yl)-propan-1-one | 23592-72-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 1-(9H-carbazol-1-yl)-propan-1-one
• 英文别名: 1-Propionyl-carbazol；1-carbazol-1-yl-propan-1-one；1-(9H-carbazol-1-yl)propan-1-one
• CAS: 23592-72-5
• 化学式: C₁₅H₁₃NO
• 分子量: 223.274
• InChiKey: UYQHZZMFVNREGQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  32.9
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4-hydroxy-5-methylpyrido[3,2,1-jk]carbazol-6-one 在 哌啶 作用下， 230.0 ℃ 、800.0 kPa 条件下， 反应 8.0h， 以51%的产率得到1-(9H-carbazol-1-yl)-propan-1-one
  参考文献：
  名称：

  吡啶并[3,2,1- jk ]咔唑-6-一的胺化

  摘要：

  用苯胺或苄胺将4-羟基吡啶并咔唑酮1胺化，得到4-胺3的产率很高。用哌啶在密封管中从4-羟基-或4-氯-5-烷基吡啶并咔唑酮1或4开环得到1-酰基咔唑5。仅4-羟基-5-苯基-吡啶并咔唑酮1d给出4-胺6。通过催化氢化或在两步合成中通过磷腈8还原4-叠氮吡啶并咔唑酮7得到4-氨基吡啶并咔唑酮9。胺9也可从苄胺3中获得通过催化脱苄基作用。4-羟基-5- phenylpyridocarbazolone的一个步骤胺化1D 通过脱苄基化至9d中是通过用苄基氯化铵反应观察到。在升高的温度下，从1d开始形成高度熔融的6,13b-二氮杂茚并[1,2,3- hi ] chrysenone 10。

  DOI：

  10.1002/jhet.5570430110

文献信息

• Electrophotographic light-sensitive media
  申请人：Canon Inc.

  公开号：EP0034497A1

  公开（公告）日：1981-08-26

  An electrophotographic light-sensitive medium is described comprising a light-sensitive layer containing a dis-azo compound represented by Formula (1) wherein A represents a coupler having aromatic properties e.g. a group represented by wherein X is a group capable of being condensed with the benzene ring of Formula (2) to form a naphthalene ring, an anthracene ring, a carbazole ring or a dibenzofuran ring, and R is -CONR, R2 or -COOR2, wherein R, is a group selected from hydrogen, a substituted or unsubstituted alkyl group, and a substituted or unsubstituted phenyl group, and R2 is a group selected from a substituted or unsubstituted alkyl group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, a substituted or unsubstituted pyridyl group, and a substituted or unsubstituted hydrazino group.

  描述了一种电子照相感光介质，该介质包括一个感光层，其中含有由式（1）表示的二偶氮 化合物 其中 A 代表具有芳香特性的耦合剂，例如由以下式子表示的基团 其中 X 是能够与式（2）的苯环缩合形成萘环、蒽环、咔唑环或二苯并呋喃环的基团，R 是-CONR、R2 或-COOR2，其中 R 是选自氢、取代或未取代的烷基、和取代或未取代的苯基，而 R2 是选自取代或未取代的烷基、取代或未取代的苯基、取代或未取代的萘基、取代或未取代的吡啶基和取代或未取代的肼基的基团。
• Alpha-type titanyl phthalocyanine composition, method for production thereof, and electrophotographic sensitive material using same
  申请人：MITA INDUSTRIAL CO. LTD.

  公开号：EP0314100A2

  公开（公告）日：1989-05-03

  The first aspect of this invention resides in providing an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and metal-­free phthalocyanine. This α-type titanyl phthalocyanine composition is stable, wide in range of absorption wavelengths, and high in spectral sensitivity because it contains an α-type titanyl phthalocyanine in combination with metal-free phthalocyanine. The second aspect of this invention resides in providing a method for the production of an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine, which method comprises pigmenting a concentrated sulfuric acid solution containing at least titanyl phthalocyanine by the acid paste process consisting in pouring said concentrated sulfuric acid solution into water. By this method, an α-type titanyl phthalocyanine composition stable to withstand the impact of aging can be easily produced. The third aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalo­cyanine and a metal-free phthalocyanine. This electro­ photographic sensitive material excels in charging property and dark attenuation property and exhibits high sensitivity and sparing residual potential. The fourth aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine composition and an electric charge transferring material exhibiting oxidation potential in the range of 0.45 to 0.65 eV. This electrophotographic sensitive material enjoys high sensitivity and shows sparing residual potential.

  本发明的第一个方面是提供一种由α型钛酞菁和无金属酞菁组成的α型钛酞菁组合物。这种 α 型钛酞菁组合物稳定，吸收波长范围宽，光谱灵敏度高，因为它含有 α 型钛酞菁和无金属酞菁。 本发明的第二个方面是提供一种生产由 α 型钛酞菁和无金属酞菁组成的 α 型钛酞菁组合物的方法，该方法包括通过酸浆工艺将至少含有钛酞菁的浓硫酸溶液颜料化，酸浆工艺包括将所述浓硫酸溶液倒入水中。通过这种方法，可以很容易地生产出稳定的 α 型钛酞菁组合物，以抵御老化的影响。 本发明的第三个方面是提供一种电致发光感光材料，它在导电基底上叠加了由 α 型钛酞菁和无金属酞菁组成的感光层。这种电致发光感光材料具有优异的充电性能和暗衰减性能，并表现出高灵敏度和无残留电位。 本发明的第四个方面是提供一种电致发光感光材料，该材料在导电基底上叠加有感光层，感光层由 α 型钛酞菁成分和电荷转移材料组成，电荷转移材料的氧化电位在 0.45 至 0.65 eV 之间。这种电致发光感光材料灵敏度高，残留电位低。
• Ink for functional layer formation, method for manufacturing light emitting element, light emitting device, and electronic apparatus
  申请人：Seiko Epson Corporation

  公开号：EP2924083A1

  公开（公告）日：2015-09-30

  The ink for functional layer formation includes a first component that is a solute; and a second component with a boiling point of 280°C or higher and 350°C or lower, is a good solvent, and is at least one type selected from a group consisting of an aromatic hydrocarbon including at least two aromatic rings, aromatic glycol ether, aliphatic glycol ether, aliphatic acetate, and aliphatic ester.

  用于形成功能层的墨水包括第一种成分，它是一种溶质；以及第二种成分，它的沸点为 280°C 或更高，350°C 或更低，是一种良好的溶剂，并且至少是一种选自至少包括两个芳香环的芳香烃、芳香族乙二醇醚、脂肪族乙二醇醚、脂肪族乙酸酯和脂肪族酯组成的组的类型。
• FILM-FORMING INK, FILM-FORMING METHOD, FILM-EQUIPPED DEVICE, AND ELECTRONIC APPARATUS
  申请人：Seiko Epson Corporation

  公开号：EP3228668A1

  公开（公告）日：2017-10-11

  To provide a film-forming ink and a film formation method, capable of forming a film having a uniform thickness in an opening part included in a partition wall by suppressing or preventing seeping-up on a partition wall surface of the film-forming ink to be supplied as a liquid droplet into the opening part, and also to provide a device with a film and an electronic apparatus, each of which has a film formed using the film formation method. A film-forming ink 1 of the invention includes a film-forming material and a liquid medium in which the film-forming material is dissolved or dispersed, wherein the liquid medium contains a first component which has a viscosity of less than 20 cp and a second component which has a boiling point at an atmospheric pressure within a range of ±30°C relative to the boiling point at an atmospheric pressure of the first component and has a viscosity of 20 cp or more, and the second component is contained in an amount of 20 parts by weight or more and 500 parts by weight or less with respect to 100 parts by weight of the first component.

  本发明旨在提供一种成膜油墨和一种成膜方法，通过抑制或防止以液滴形式供应到开口部的成膜油墨在开口部的隔板壁表面渗出，从而能够在隔板壁上的开口部形成厚度均匀的薄膜，同时还提供一种具有薄膜的装置和一种电子设备，其中每种装置和设备都具有使用该成膜方法形成的薄膜。 本发明的成膜油墨 1 包括成膜材料和溶解或分散成膜材料的液体介质，其中液体介质包含粘度小于 20 cp 的第一组分和在大气压力下沸点相对于第一组分在大气压力下的沸点在 ±30°C 范围内且粘度大于等于 20 cp 的第二组分、相对于 100 重量份的第一组分，第二组分的含量为 20 重量份或以上，500 重量份或以下。
• Film-forming ink, film formation method, device with film, and electronic apparatus
  申请人：SEIKO EPSON CORPORATION

  公开号：US10557046B2

  公开（公告）日：2020-02-11

  To provide a film-forming ink and a film formation method, capable of making the dimensional accuracy of a film to be formed excellent by increasing the apparent liquid droplet amount of a film-forming ink to be supplied as a liquid droplet into an opening part included in a partition wall, and also to provide a device with a film and an electronic apparatus, each of which has a film formed using the film formation method. A film-forming ink of the invention includes a film-forming material and a liquid medium in which the film-forming material is dissolved or dispersed, wherein the liquid medium contains a first component which has a boiling point at an atmospheric pressure of 200° C. or higher and a second component which has a boiling point at an atmospheric pressure lower than the first component.

  提供一种成膜油墨和一种成膜方法，能够通过增加成膜油墨作为液滴供应到包括在隔墙中的开口部分的表观液滴量，使要形成的薄膜的尺寸精度极佳，还提供一种带有薄膜的装置和一种电子设备，其中每种装置和设备都具有使用该成膜方法形成的薄膜。本发明的成膜油墨包括一种成膜材料和一种液体介质，成膜材料溶解或分散在液体介质中，其中液体介质包含在大气压力下沸点为 200 摄氏度或更高的第一种成分和在大气压力下沸点低于第一种成分的第二种成分。