(E)-6-dodecen-1-ol | 52957-14-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-6-dodecen-1-ol
• 英文别名: (E)-dodec-6-en-1-ol；6E-Dodecen-1-ol
• CAS: 52957-14-9
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: IENBWMQKVZLORT-VOTSOKGWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  borinane 、 1-bromohept-1-yne 生成 (E)-6-dodecen-1-ol
  参考文献：
  名称：

  Pheromone Synthesis via Organoboranes: A General One-Pot Synthesis of (E)-6-Alken-1-ols

  摘要：

  DOI：

  10.1055/s-1984-31017

文献信息

• Sweet surfactants: packing parameter-invariant amphiphiles as emulsifiers and capping agents for morphology control of inorganic particles
  作者：Michael Voggel、Rebecca M. Meinusch、Vanessa Siewert、Marius Kunkel、Valentin Wittmann、Sebastian Polarz

  DOI：10.1039/c8sm01091a

  日期：——

  Exploration of isomer effects on amphiphile properties (e.g.emulsification and as nanoparticle growth modifiers) using a library of glycoside-based surfactants.

  对异构体对两性分子性质（如乳化和作为纳米粒子生长调节剂）的影响进行探索，使用基于糖苷的表面活性剂库。
• AGRICULTURAL PHEROMONE COMPOSITIONS COMPRISING POSITIONAL ISOMERS
  申请人：PROVIVI, INC.

  公开号：US20170135343A1

  公开（公告）日：2017-05-18

  The present disclosure provides pheromone compositions. In some aspects, the compositions taught herein comprise a pheromone chemically corresponding to the pheromone naturally produced by a given insect, along with at least one positional isomer of said pheromone. In various aspects, pheromone compositions of the present disclosure are able to modulate the response of the insect based on the ratio of natural pheromone to its positional isomer.

  本公开提供信息素组合物。在某些方面，本文所教授的组合物包括一种与某种昆虫自然产生的信息素在化学上相对应的信息素，以及至少一种该信息素的位置异构体。在各个方面，本公开的信息素组合物能够通过自然信息素与其位置异构体的比例来调节昆虫的反应。
• Tandem decarboxylative hydroformylation–hydrogenation reaction of α,β-unsaturated carboxylic acids toward aliphatic alcohols under mild conditions employing a supramolecular catalyst system
  作者：Lisa Diab、Urs Gellrich、Bernhard Breit

  DOI：10.1039/c3cc45547e

  日期：——

  under mild reaction conditions, compatible with a wide range reactive functional groups, is reported. The new methodology consists of a novel tandem decarboxylative hydroformylation/aldehyde reduction sequence employing a unique supramolecular catalyst system.

  报道了一种新的原子经济催化方法，该方法可在温和的反应条件下将α，β-不饱和羧酸高度化学选择性还原为相应的饱和醇，并与广泛的反应性官能团相容。新方法包括采用独特的超分子催化剂体系的新型串联脱羧加氢甲酰化/醛还原序列。
• MULTI-SUBSTRATE METABOLISM FOR IMPROVING BIOMASS AND LIPID PRODUCTION
  申请人：Provivi, Inc.

  公开号：EP3564377A1

  公开（公告）日：2019-11-06

  The present application relates to methods to improve biomass or lipid production in a microorganism from one or more fatty acid and one or more simple carbon co-substrates. Produced lipids may include unsaturated C6-C24 fatty acids, alcohols, aldehydes, and acetates which may be useful as final products or precursors to insect pheromones, fragrances, flavors, and polymer intermediates. The application further relates to recombinant microorganisms modified for improved production of biomass or lipid, or improved lipid selectivity. Also provided are methods of producing one or more lipid using the recombinant microorganisms, as well as compositions comprising the recombinant microorganisms and/or optionally one or more of the product lipid.

  本申请涉及提高微生物中一种或多种脂肪酸和一种或多种单碳共底物的生物量或脂质产量的方法。生产的脂质可包括不饱和 C6-C24 脂肪酸、醇、醛和乙酸酯，它们可用作昆虫信息素、香料、香精和聚合物中间体的最终产品或前体。本申请还涉及为改进生物质或脂质的生产或改进脂质选择性而改良的重组微生物。还提供了使用重组微生物生产一种或多种脂质的方法，以及包含重组微生物和/或一种或多种产品脂质的组合物。
• Surfactants based on monounsaturated fatty alcohol derivatives
  申请人：Stepan Company

  公开号：US10287530B2

  公开（公告）日：2019-05-14

  Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C10-C12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.

  本发明公开了由 C10-C12 单不饱和醇的烷氧基化物、硫酸盐或硫酸醚组成的表面活性剂组合物。烷氧基化物、硫酸盐或硫酸醚可以来自十一碳烯酸或十一碳烯醇。与饱和类似物相比，单不饱和烷氧基化物、硫酸盐和醚硫酸盐的刺激性较小，因此在个人护理、洗衣、清洁剂和其他家居应用中很有价值。显微镜研究表明，烷氧基化物、硫酸盐和醚硫酸盐在活性成分含量较高的情况下具有良好的相行为，从而为具有更高压缩性的产品提供了更多机会。当与阳离子表面活性剂结合使用时，烷氧基化物、硫酸盐和醚硫酸盐可发挥协同作用，与饱和类似物相比，它们的溶解度更高。这些表面活性剂在个人护理、洗衣和清洁、乳液聚合、农产品、油田应用和特种泡沫等行业中都有应用价值。