9,10-双(苯基乙炔)-1,5-二氯蒽 | 51580-24-6

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 中文名称: 9,10-双(苯基乙炔)-1,5-二氯蒽
• 英文名称: 1,5-dichloro-9,10-bis(phenylethynyl)anthracene
• 英文别名: 1,5-dichloro-9,10-bis(2-phenylethynyl)anthracene
• CAS: 51580-24-6
• 化学式: C₃₀H₁₆Cl₂
• 分子量: 447.363
• InChiKey: DCCXNTCSVXAHAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903999090

反应信息

• 作为产物：
  描述：

  1,5-dichloro-9,10-bis(phenylethynyl)-9,10-dihydroanthracene-9,10-diol 在 tin(ll) chloride 作用下， 以 溶剂黄146 为溶剂， 以72%的产率得到9,10-双(苯基乙炔)-1,5-二氯蒽
  参考文献：
  名称：

  Hanhela, Peter J.; Paul, Brenton D., Australian Journal of Chemistry, 1981, vol. 34, # 8, p. 1701 - 1717

  摘要：

  DOI：

文献信息

• Blue/violet diphenylanthracene chemiluminescent fluorescers
  申请人：Cranor Earl

  公开号：US20100327240A1

  公开（公告）日：2010-12-30

  Compounds are disclosed for the production of chemiluminescent light, particularly for the production of blue/violet light within the range of about 390 nm to less than 438 nm, and most particularly to the use of compounds composed of symmetrically and asymmetrically substituted anthracenes which are effective for increasing the production of such blue/violet light when used as fluorescers in conjunction with chemiluminescent systems. These systems utilize derivatives of 9,10-diphenylanthracene containing one or more fluorines As shown in General Formulae 1-3. The variables shown in Formulae 1-3 are defined in the specification.

  揭示了用于生产化学发光灯的化合物，特别是用于在约390纳米至不到438纳米范围内产生蓝/紫光的化合物，尤其是使用由对称和非对称取代的蒽组成的化合物，这些化合物在与化学发光系统一起作为荧光剂时有效地增加了这种蓝/紫光的产生。这些系统利用含有一个或多个氟的9,10-二苯基蒽衍生物，如通用公式1-3所示。公式1-3中显示的变量在说明书中有定义。
• A method for protecting the liquid components of a chemiluminescent system and a chemiluminescent light-generating system thus protected
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0011911A1

  公开（公告）日：1980-06-11

  In a chemiluminescent lighting system having separated components in storage before use, at least one of the separate components is stored in a container made from a laminate of polypropylene film and aluminium foil. Good stability of both oxalate ester components and hydroperoxide components when stored in such containers is demonstrated.

  在一种化学发光照明系统中，在使用前的贮存过程中，其组分是分开的，其中至少有一种组分是贮存在一个由聚丙烯薄膜和铝箔层压板制成的容器中。事实证明，草酸酯成分和过氧化氢成分在这种容器中储存时具有良好的稳定性。
• Novel N,N'-bis(trifluoromethylsulfonyl)oxamides, chemiluminescent compositions containing them and processes for generating chemiluminescence employing said compositions
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0010844A1

  公开（公告）日：1980-05-14

  Novel N,N'-bis(trifluoromethylsulfonyl)oxamides of the formula (I) wherein R and R' have the meaning given in the description (preferably chlorinated phenyl or pyridyl, nitrophenyl or methoxyethyl), when used in compositions comprising also an organic fluorescer such as 1-chloro-9,10-bis(phe- nylethynyl)-anthracene and a diluent such as dibutyl phthalate, will furnish chemiluminescent light with good light intensity and quantum efficiency upon reaction with a peroxide component such as hydrogen peroxide. The preparation of the compounds of the formula (I) is described; e.g. the particulary preferred compound N,N'-bis(2,4,5-trichlorophenyl)-N,N'-bis-trifluoromethylsulfonyl)-oxamide is prepared on the following way:

  新颖的 N,N'-双(三氟甲基磺酰基)草酰胺，其式为(I) 其中 R 和 R'具有说明中给出的含义（最好是氯化苯基或吡啶基、硝基苯基或甲氧基乙基），当用于包含以下成分的组合物中时 当与过氧化物成分（如过氧化氢）反应时，将产生光强度和量子效率良好的化学发光。例如，N,N'-双（2,4,5-三氯苯基）-N,N'-双三氟甲基磺酰基）-氧酰胺的制备方法如下：
• Enhanced aqueous chemiluminescent systems
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0096749A1

  公开（公告）日：1983-12-28

  Aqueous chemiluminescent systems are found to have improved chemiluminescence due to presence of surfactants in minor amounts.

  水性化学发光体系由于含有少量的表面活性剂，其化学发光效果有所改善。
• Use of water-soluble polymers in aqueous chemical light formulations
  申请人：AMERICAN CYANAMID COMPANY

  公开号：EP0175889A1

  公开（公告）日：1986-04-02

  Aqueous chemiluminescent systems have been found to exhibit improved chemiluminescence due to the presence of minor amounts of a water-soluble polymer.

  研究发现，水性化学发光体系由于含有少量水溶性聚合物，其化学发光性能有所改善。