5,6-tridecadiene | 110211-23-9

• 分子结构分类: 有机化合物 - 叠烯 - 无环联烯
• 英文名称: 5,6-tridecadiene
• CAS: 110211-23-9
• 化学式: C₁₃H₂₄
• 分子量: 180.334
• InChiKey: GQYIOWAUAFXLBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  tridec-5-yn-7-ol 在 三氯化铁 、 三苯基膦 甲醇 、 samarium diiodide 作用下， 以 四氢呋喃 为溶剂， 反应 0.25h， 以95%的产率得到(Z)-5-Tridecen-7-ol
  参考文献：
  名称：

  Selective reduction of alkynes by the reagent Sml2 - Transition metal catalysts - proton donors

  摘要：

  Alkynes were selectively reduced to cis-olefins under mild conditions by Sml2 in admixture with first-row transition metal catalysts and appropriate proton donors, in which the corresponding transition metal hydrides are presumed as the reactive species. The conditions also effected the conversion of 1,6-diynes to the corresponding five-membered carbocycles.

  DOI：

  10.1016/0040-4039(91)80083-i

文献信息

• Palladium-catalyzed reduction of propargylic acetates with SmI2. A mild and convenient method for the preparation of allenes
  作者：Takanori Tabuchi、Junji Inanaga、Masaru Yamaguchi

  DOI：10.1016/s0040-4039(00)85178-3

  日期：1986.1

  A highly regioselective reduction of propargylic acetates has been attained by using SmI2 and catalytic Pd(0) in the presence of 2,4-dimethyl-3-pentanol affording various types of allenes in high yields.

  在2,4-二甲基-3-戊醇的存在下，通过使用SmI 2和催化Pd（0），可以实现高炔丙基乙酸的高度区域选择性还原，从而以高收率提供各种类型的丙二烯。
• Selective reduction of alkynes by the reagent Sml2 - Transition metal catalysts - proton donors
  作者：Junji Inanaga、Yasuo Yokoyama、Yoshiyasu Baba、Masaru Yamaguchi

  DOI：10.1016/0040-4039(91)80083-i

  日期：1991.9

  Alkynes were selectively reduced to cis-olefins under mild conditions by Sml2 in admixture with first-row transition metal catalysts and appropriate proton donors, in which the corresponding transition metal hydrides are presumed as the reactive species. The conditions also effected the conversion of 1,6-diynes to the corresponding five-membered carbocycles.