N,N'-bis(2,3,4,5,6-pentafluorobenzyl)-1,7-dicyano-perylene-3,4:9,10-bis(dicarboximide) | 1020819-08-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis(2,3,4,5,6-pentafluorobenzyl)-1,7-dicyano-perylene-3,4:9,10-bis(dicarboximide)
• 英文别名: 6,8,17,19-Tetraoxo-7,18-bis[(2,3,4,5,6-pentafluorophenyl)methyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-11,22-dicarbonitrile；6,8,17,19-tetraoxo-7,18-bis[(2,3,4,5,6-pentafluorophenyl)methyl]-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(22),2,4,9,11,13(23),14,16(24),20,25-decaene-11,22-dicarbonitrile
• CAS: 1020819-08-2
• 化学式: C₄₀H₁₀F₁₀N₄O₄
• 分子量: 800.528
• InChiKey: YBMJIELKCOSXBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  58
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  122
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  N,N'-bis(2,3,4,5,6-pentafluorobenzyl)-1,7-dibromo-perylene-3,4:9,10-bis(dicarboximide) 、 氰化锌 在 tris-(dibenzylideneacetone)dipalladium(0) 作用下， 以88%的产率得到N,N'-bis(2,3,4,5,6-pentafluorobenzyl)-1,7-dicyano-perylene-3,4:9,10-bis(dicarboximide)
  参考文献：
  名称：

  Organic n-Channel Transistors Based on Core-Cyanated Perylene Carboxylic Diimide Derivatives

  摘要：

  Five core-cyanated perylene carboxylic diimides end-functionalized with fluorine-containing linear and cyclic substituents have been synthesized and employed in the fabrication of air-stable n-channel organic thin-film field-effect transistors with carrier mobilities up to 0.1 cm(2)/Vs. The relationships between molecular structure, thin-film morphology, substrate temperature during vacuum deposition, transistor performance, and air stability have been investigated. Our experiments led us to conclude that the role of the fluorine functionalization in the air-stable n-channel operation of the transistors is different than previously thought.

  DOI：

  10.1021/ja074675e

文献信息

• Organic n-Channel Transistors Based on Core-Cyanated Perylene Carboxylic Diimide Derivatives
  作者：R. Thomas Weitz、Konstantin Amsharov、Ute Zschieschang、Esther Barrena Villas、Dipak K. Goswami、Marko Burghard、Helmut Dosch、Martin Jansen、Klaus Kern、Hagen Klauk

  DOI：10.1021/ja074675e

  日期：2008.4.1

  Five core-cyanated perylene carboxylic diimides end-functionalized with fluorine-containing linear and cyclic substituents have been synthesized and employed in the fabrication of air-stable n-channel organic thin-film field-effect transistors with carrier mobilities up to 0.1 cm(2)/Vs. The relationships between molecular structure, thin-film morphology, substrate temperature during vacuum deposition, transistor performance, and air stability have been investigated. Our experiments led us to conclude that the role of the fluorine functionalization in the air-stable n-channel operation of the transistors is different than previously thought.