2[(4,4,4,3,3,2,2-heptafluorobutoxy)methyl]oxirane | 648-43-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 2[(4,4,4,3,3,2,2-heptafluorobutoxy)methyl]oxirane
• 英文别名: 1-(2,3-epoxy-propoxy)-1H,1H-heptafluoro-butane；1-(2,3-Epoxy-propoxy)-1H,1H-heptafluor-butan；2-[(2,2,3,3,4,4,4-Heptafluorobutoxy)methyl]oxirane；2-(2,2,3,3,4,4,4-heptafluorobutoxymethyl)oxirane
• CAS: 648-43-1
• 化学式: C₇H₇F₇O₂
• 分子量: 256.12
• InChiKey: SRPBEKWTJQBCPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  2[(4,4,4,3,3,2,2-heptafluorobutoxy)methyl]oxirane 在 硫脲 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以49%的产率得到2[(4,4,4,3,3,2,2-heptafluorobutoxy)methyl]thiirane
  参考文献：
  名称：

  [(Polyfluoroalkoxy)methyl]thiiranes and 2-anilinoethanethiols

  摘要：

  By reaction of appropriate oxiranes with thiourea [(polyfluoroalkoxy)methyl]-substituted thiiranes were obtained that are key compounds for the synthesis of perfluoro-containing 1,2-aminopropanethiols.

  DOI：

  10.1134/s1070428008070026
• 作为产物：
  描述：

  3-(4,4,4,,3,3,2,2-heptafluorobutoxy)-1-chloropropan-2-ol 在 氢氧化钾 作用下， 以 乙醚 为溶剂， 反应 1.5h， 以43%的产率得到2[(4,4,4,3,3,2,2-heptafluorobutoxy)methyl]oxirane
  参考文献：
  名称：

  [(Polyfluoroalkoxy)methyl]thiiranes and 2-anilinoethanethiols

  摘要：

  By reaction of appropriate oxiranes with thiourea [(polyfluoroalkoxy)methyl]-substituted thiiranes were obtained that are key compounds for the synthesis of perfluoro-containing 1,2-aminopropanethiols.

  DOI：

  10.1134/s1070428008070026

文献信息

• COMPOSITION AND PROCESS FOR PREPARING CURABLE ORGANOFLUORINE-MODIFIED POLYSILAZANES, AND POLYSILAZANES PREPARED THEREBY
  申请人：Yang Yu

  公开号：US20100331498A1

  公开（公告）日：2010-12-30

  A composition for preparing curable organofluorine-modified polysilazanes comprises (a) at least one curable oligomeric or polymeric polysilazane comprising at least one chemically reactive site; and (b) at least one fluorochemical compound comprising (1) at least one organofluorine or heteroorganofluorine moiety, and (2) at least one functional group that is capable of reacting with the curable oligomeric or polymeric polysilazane through at least one of the chemically reactive sites of the polysilazane. The curable organofluorine-modified polysilazanes can be prepared by combining the components of the composition and allowing or inducing the components to react.

  一种制备可固化有机氟改性聚硅氮烷的组合物，包括(a)至少一种可固化的低聚或高聚聚硅氮烷，其包含至少一个化学反应位点；以及(b)至少一种含氟化学物质，包括(1)至少一个有机氟或杂原子有机氟基团，以及(2)至少一个功能基团，能够通过聚硅氮烷的至少一个化学反应位点与可固化低聚或高聚聚硅氮烷反应。可固化的有机氟改性聚硅氮烷可以通过混合组合物的组分并允许或诱导组分反应而制备。
• Brey; Tarrant, Journal of the American Chemical Society, 1957, vol. 79, p. 6533,6534,6536
  作者：Brey、Tarrant

  DOI：——

  日期：——
• US4508916A
  申请人：——

  公开号：US4508916A

  公开（公告）日：1985-04-02
• US8324324B2
  申请人：——

  公开号：US8324324B2

  公开（公告）日：2012-12-04
• [EN] COMPOSITION AND PROCESS FOR PREPARING CURABLE ORGANOFLUORINE-MODIFIED POLYSILAZANES, AND POLYSILAZANES PREPARED THEREBY<br/>[FR] COMPOSITION ET PROCÉDÉ PERMETTANT DE PRÉPARER DES POLYSILAZANES MODIFIÉS PAR UN ORGANOFLUOR DURCISSABLES, ET POLYSILAZANES AINSI PRÉPARÉS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2011002666A1

  公开（公告）日：2011-01-06

  A composition for preparing curable organofluorine-modified polysilazanes comprises (a) at least one curable oligomeric or polymeric polysilazane comprising at least one chemically reactive site; and (b) at least one fluorochemical compound comprising (1) at least one organofluorine or heteroorganofluorine moiety, and (2) at least one functional group that is capable of reacting with the curable oligomeric or polymeric polysilazane through at least one of the chemically reactive sites of the polysilazane. The curable organofluorine-modified polysilazanes can be prepared by combining the components of the composition and allowing or inducing the components to react.