4-ethyl-2,3-diphenylquinoline | 42455-94-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 4-ethyl-2,3-diphenylquinoline
• 英文别名: 2-Methyl-1,4,5-triphenylpyrrol；5-methyl-1,2,3-triphenyl-pyrrole；5-Methyl-1,2,3-triphenylpyrrole
• CAS: 42455-94-7
• 化学式: C₂₃H₁₉N
• 分子量: 309.411
• InChiKey: XEZVPXNZUAHGTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (Z)-(1-bromo-n-pent-1-en-3-yne-1,2-diyl)dibenzene 、 3,5-二甲氧基苯胺 在 tris-(dibenzylideneacetone)dipalladium(0) 、 双(2-二苯基磷苯基)醚 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以57%的产率得到4-ethyl-2,3-diphenylquinoline
  参考文献：
  名称：

  锗-二溴苯炔与苯胺的钯催化分子间多米诺反应 一锅法合成喹啉和喹啉酮

  摘要：

  摘要 描述了一种有效的多米诺骨牌工艺，包括钯催化的烯基溴化的胺化反应，1,5-H转移，6- exo - dig亲电环化的环化反应以及钯催化的醚化反应。该反应提供了由宝石-二溴代苯乙炔和苯胺有效地一锅法合成多取代喹啉和喹啉酮的方法。 描述了一种有效的多米诺骨牌工艺，包括钯催化的烯基溴化的胺化反应，1,5-H转移，6- exo - dig亲电环化的环化反应以及钯催化的醚化反应。该反应提供了由宝石-二溴代苯乙炔和苯胺有效地一锅法合成多取代喹啉和喹啉酮的方法。

  DOI：

  10.1055/s-0032-1316613

文献信息

• Organic electroluminescence device
  申请人：UDC Ireland

  公开号：US10454042B2

  公开（公告）日：2019-10-22

  An object of the present invention is to provide an organic electroluminescence device having excellent light emission efficiency and durability, in particular, durability when driving at a high temperature. Provided is an organic electroluminescence device including on a substrate a pair of electrodes, and at least one layer of an organic layer including a light emitting layer containing a light emitting material disposed between the electrodes, wherein the light emitting layer includes at least each one of specific indolocarbazole derivatives and specific condensed ring metal complexes.

  本发明的目的是提供一种有机电致发光器件，该器件具有优异的发光效率和耐用性，特别是在高温驱动时的耐用性。本发明提供了一种有机电致发光器件，包括在基底上的一对电极，以及至少一层有机层，该有机层包括设置在电极之间的包含发光材料的发光层，其中发光层包括特定吲哚咔唑衍生物和特定缩合环金属配合物中的至少一种。
• COMPOUND FOR ORGANIC ELECTROLUMINESCENT ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Nippon Steel Chemical Co., Ltd.

  公开号：EP1956022B1

  公开（公告）日：2012-07-25
• Compound for Use in Organic Electroluminescent Device and Organic Electroluminescent Device
  申请人：Komori Masaki

  公开号：US20090302742A1

  公开（公告）日：2009-12-10

  Disclosed are an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, fully secured of driving stability, and simple in constitution and a compound for use therein. The organic electroluminescent device comprises a light-emitting layer disposed between an anode and a cathode piled one upon another on a substrate and the light-emitting layer contains a phosphorescent dopant and a compound for use in an organic electroluminescent device having two or more indolocarbazole skeletons as a host material. An example of the compound having indolocarbazole skeletons for use in the device is expressed by the following formula.
• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Fukuzaki Eiji

  公开号：US20120153272A1

  公开（公告）日：2012-06-21

  An object of the present invention is to provide an organic electroluminescence device having excellent light emission efficiency and durability, in particular, durability when driving at a high temperature. Provided is an organic electroluminescence device including on a substrate a pair of electrodes, and at least one layer of an organic layer including a light emitting layer containing a light emitting material disposed between the electrodes, wherein the light emitting layer includes at least each one of specific indolocarbazole derivatives and specific condensed ring metal complexes.
• US7993760B2
  申请人：——

  公开号：US7993760B2

  公开（公告）日：2011-08-09