11-methyl-9,14-diphenyldibenzo[de,qr]tetracene | 1486514-73-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 11-methyl-9,14-diphenyldibenzo[de,qr]tetracene
• 英文别名: 6-Methyl-3,10-diphenylhexacyclo[10.10.2.02,11.04,9.016,24.019,23]tetracosa-1(22),2,4(9),5,7,10,12,14,16(24),17,19(23),20-dodecaene；6-methyl-3,10-diphenylhexacyclo[10.10.2.02,11.04,9.016,24.019,23]tetracosa-1(22),2,4(9),5,7,10,12,14,16(24),17,19(23),20-dodecaene
• CAS: 1486514-73-1
• 化学式: C₃₇H₂₄
• 分子量: 468.598
• InChiKey: LFWWKWRGSWOVLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  37
• 可旋转键数：
  2
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9,11-diphenyl-10H-cyclopenta[e]pyren-10-one 、 2-氨基-4-甲基苯甲酸 以 1,2-二氯乙烷 为溶剂， 以25%的产率得到11-methyl-9,14-diphenyldibenzo[de,qr]tetracene
  参考文献：
  名称：

  Substituent effects in twisted dibenzotetracene derivatives: Blue emitting materials for organic light-emitting diodes

  摘要：

  A series of dibenzotetracene derivatives containing different substituents at the 11-,12-positions have been successfully synthesized and characterized. Single crystal X-ray analysis indicates that the new molecules have a twisted structure, which can effectively decrease the intermolecular aggregation in the solid-state. The effect of both substitueut and packing on the corresponding physical properties was also investigated. In addition, organic light-emitting diodes doped with 11,12-difluoro-9,14-diphenyl-dibenzo [de,qr]tetracene into the emitter 9,9'-(1,3-phenylene)bis-9H-carbazole were fabricated and exhibit good performance. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.07.007

文献信息

• Substituent effects in twisted dibenzotetracene derivatives: Blue emitting materials for organic light-emitting diodes
  作者：Jinchong Xiao、Zhenying Liu、Xuemin Zhang、Weichen Wu、Tiejun Ren、Bo Lv、Li Jiang、Xuefei Wang、Hua Chen、Wenming Su、Jianwen Zhao

  DOI：10.1016/j.dyepig.2014.07.007

  日期：2015.1

  A series of dibenzotetracene derivatives containing different substituents at the 11-,12-positions have been successfully synthesized and characterized. Single crystal X-ray analysis indicates that the new molecules have a twisted structure, which can effectively decrease the intermolecular aggregation in the solid-state. The effect of both substitueut and packing on the corresponding physical properties was also investigated. In addition, organic light-emitting diodes doped with 11,12-difluoro-9,14-diphenyl-dibenzo [de,qr]tetracene into the emitter 9,9'-(1,3-phenylene)bis-9H-carbazole were fabricated and exhibit good performance. (C) 2014 Elsevier Ltd. All rights reserved.