3,6,9,12,15,18,21,24,27-Nonaoxatriacontanoyl fluoride, 2,4,4,5,7,7,8,10,10,11,13,13,14,16,16,17,19,19,20,22,22,23,25,25,26,28,28,29,29,30,30,30-dotriacontafluoro-2,5,8,11,14,17,20,23,26-nonakis(trifluoromethyl)- | 65150-88-1

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: 3,6,9,12,15,18,21,24,27-Nonaoxatriacontanoyl fluoride, 2,4,4,5,7,7,8,10,10,11,13,13,14,16,16,17,19,19,20,22,22,23,25,25,26,28,28,29,29,30,30,30-dotriacontafluoro-2,5,8,11,14,17,20,23,26-nonakis(trifluoromethyl)-
• 英文别名: 2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]propoxy]propoxy]propoxy]propoxy]propoxy]propoxy]propanoyl fluoride
• CAS: 65150-88-1
• 化学式: C₃₀F₆₀O₁₀
• 分子量: 1660.23
• InChiKey: JAKFVMIZGKDDLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.6
• 重原子数：
  100
• 可旋转键数：
  28
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  100
• 氢给体数：
  0
• 氢受体数：
  70

反应信息

• 作为反应物：
  描述：

  氨基胍半硫酸盐 、 3,6,9,12,15,18,21,24,27-Nonaoxatriacontanoyl fluoride, 2,4,4,5,7,7,8,10,10,11,13,13,14,16,16,17,19,19,20,22,22,23,25,25,26,28,28,29,29,30,30,30-dotriacontafluoro-2,5,8,11,14,17,20,23,26-nonakis(trifluoromethyl)- 以 1,1,2-三氯三氟乙烷（CFC-113） 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  Vershilov, S. V.; Popova, L. M.; Mungalov, V. E., Russian Journal of Organic Chemistry, 1994, vol. 30, # 8, p. 1304 - 1307

  摘要：

  DOI：

文献信息

• Carboxylic acid ester compound having polymerizable functional group and fluorine atom group, and method for producing same
  申请人：UNIMATEC CO., LTD.

  公开号：US10125107B1

  公开（公告）日：2018-11-13

  Provided are a fluorine-containing monomer capable of being dissolved in a general organic solvent such as a hydrocarbon solvent and simultaneously having excellent water and oil repellency, and a method for producing the fluorine-containing monomer. The fluorine-containing monomer is a carboxylic acid ester compound having a polymerizable functional group and a fluorine atom group, represented by the following general formula: CaF2a+1O—(CbF2bO)c—C2F4COOR. The method is a process for producing the carboxylic acid ester compound, characterized by that any one of an isocyanulate derivative, a phthalic acid derivative and a cycloalkane dialcohol modified (meth)acrylate each having a terminal hydroxyl group is made to react with a perfluoropolyether carboxylic acid halide.

  提供了一种含氟单体，能够溶解在一般有机溶剂（如烃类溶剂）中，同时具有优异的防水和防油性能，以及一种制备含氟单体的方法。该含氟单体是一种具有聚合功能基团和氟原子基团的羧酸酯化合物，由下列通式表示：CaF2a+1O—(CbF2bO)c—C2F4COOR。该方法是一种生产羧酸酯化合物的过程，其特征在于，使用具有末端羟基的异氰酸酯衍生物、邻苯二甲酸衍生物和环烷二醇改性（甲）基丙烯酸酯之一，与全氟聚醚羧酸卤化物反应。
• CARBOXYLIC ACID ESTER COMPOUND HAVING POLYMERIZABLE FUNCTIONAL GROUP AND FLUORINE ATOM GROUP, AND METHOD FOR PRODUCING SAME
  申请人：Unimatec Co., Ltd.

  公开号：EP3395794A1

  公开（公告）日：2018-10-31

  Provided are a fluorine-containing monomer having excellent water repellency and oil repellency that can be dissolved in common organic solvents such as hydrocarbon solvents, and a method for producing the same. A carboxylic acid ester compound having a polymerizable functional group and a fluorine atom group represented by the following general formula. CaF2a+1O-(CbF2bO)c-C2F4COOR Also, a method for producing the carboxylic acid ester compound characterized by reacting any one of an isocyanurate derivative having an end hydroxyl group, a phthalic acid derivative, and a cycloalkane dialcohol-modified (meth)acrylate, with a perfluoropolyether carboxylic acid halide.

  本发明提供了一种具有优异憎水性和憎油性、可溶解于普通有机溶剂（如烃类溶剂）的含氟单体，以及生产该单体的方法。一种羧酸酯化合物，其可聚合官能团和氟原子基团由以下通式表示。CaF2a+1O-(CbF2bO)c-C2F4COOR 还有，生产该羧酸酯化合物的方法，其特征在于使具有端羟基的异氰尿酸酯衍生物、邻苯二甲酸衍生物和环烷二醇改性(甲基)丙烯酸酯中的任一种与全氟聚醚羧酸卤化物反应。