P(CH2-o-C6H4O(CH2)4CH=CH2)3 | 1238221-38-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: P(CH2-o-C6H4O(CH2)4CH=CH2)3
• 英文别名: Tris[(2-hex-5-enoxyphenyl)methyl]phosphane；tris[(2-hex-5-enoxyphenyl)methyl]phosphane
• CAS: 1238221-38-9
• 化学式: C₃₉H₅₁O₃P
• 分子量: 598.806
• InChiKey: WOLIQWXIEIBTHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  43
• 可旋转键数：
  24
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 P(CH2-o-C6H4O(CH2)4CH=CH2)3 以 not given 为溶剂， 以60%的产率得到trans-PdCl2(P[CH2-o-C6H4O(CH2)4CH=CH2]3)2
  参考文献：
  名称：

  Square-Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH₂)₄CH═CH₂ Substituents; Two- and Three-Fold Intramolecular Ring-Closing Metatheses

  摘要：

  When trans-PdCl2{PPhn[CH2C6H4O(CH2)(4)CH= CH2](3-n)}(2), with ortho or meta C6H4 linkages and n = 0, 1 (tribenzyl- or dibenzylphenylphosplune cores), are treated with Grubbs' catalyst and then H-2/PtO2 the macrocycles trans-PdCl2{P[CH2-o-C6H4O(CH2)(10)O-o-C6H4CH2][CH2-o-C6H4O (CH2)(10)O-o-C6H4)CH2] P[CH2-o-C6H4O(CH2)(10)O-o-C6H4CH2]}, trans-PdCl2{PPh[CH2C6H4O(CH2)(10)OC6H4OCH2]}(2) (o- or m-C6H4), and trans- PdCl2{PPh[CH2-m-C6H4O(CH2)(10)O-m-C6H4CH2]}(2)Ph P} are isolated in high yields

  DOI：

  10.1021/om100536g
• 作为产物：
  描述：

  在 magnesium 、 三氯化磷 作用下， 以 四氢呋喃 为溶剂， 以63%的产率得到P(CH2-o-C6H4O(CH2)4CH=CH2)3
  参考文献：
  名称：

  Square-Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH₂)₄CH═CH₂ Substituents; Two- and Three-Fold Intramolecular Ring-Closing Metatheses

  摘要：

  When trans-PdCl2{PPhn[CH2C6H4O(CH2)(4)CH= CH2](3-n)}(2), with ortho or meta C6H4 linkages and n = 0, 1 (tribenzyl- or dibenzylphenylphosplune cores), are treated with Grubbs' catalyst and then H-2/PtO2 the macrocycles trans-PdCl2{P[CH2-o-C6H4O(CH2)(10)O-o-C6H4CH2][CH2-o-C6H4O (CH2)(10)O-o-C6H4)CH2] P[CH2-o-C6H4O(CH2)(10)O-o-C6H4CH2]}, trans-PdCl2{PPh[CH2C6H4O(CH2)(10)OC6H4OCH2]}(2) (o- or m-C6H4), and trans- PdCl2{PPh[CH2-m-C6H4O(CH2)(10)O-m-C6H4CH2]}(2)Ph P} are isolated in high yields

  DOI：

  10.1021/om100536g

文献信息

• Square-Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH₂)₄CH═CH₂ Substituents; Two- and Three-Fold Intramolecular Ring-Closing Metatheses
  作者：Jun Han、Chao Deng、Ru Fang、Deyang Zhao、Leyong Wang、John A. Gladysz

  DOI：10.1021/om100536g

  日期：2010.8.9

  When trans-PdCl2PPhn[CH2C6H4O(CH2)(4)CH= CH2](3-n)}(2), with ortho or meta C6H4 linkages and n = 0, 1 (tribenzyl- or dibenzylphenylphosplune cores), are treated with Grubbs' catalyst and then H-2/PtO2 the macrocycles trans-PdCl2P[CH2-o-C6H4O(CH2)(10)O-o-C6H4CH2][CH2-o-C6H4O (CH2)(10)O-o-C6H4)CH2] P[CH2-o-C6H4O(CH2)(10)O-o-C6H4CH2]}, trans-PdCl2PPh[CH2C6H4O(CH2)(10)OC6H4OCH2]}(2) (o- or m-C6H4), and trans- PdCl2PPh[CH2-m-C6H4O(CH2)(10)O-m-C6H4CH2]}(2)Ph P} are isolated in high yields