N-Naphthalen-1-yl-N'-((S)-1-phenyl-ethyl)-oxalamide | 816419-29-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-Naphthalen-1-yl-N'-((S)-1-phenyl-ethyl)-oxalamide
• 英文别名: N~1~-(Naphthalen-1-yl)-N~2~-[(1S)-1-phenylethyl]ethanediamide；N-naphthalen-1-yl-N'-[(1S)-1-phenylethyl]oxamide
• CAS: 816419-29-1
• 化学式: C₂₀H₁₈N₂O₂
• 分子量: 318.375
• InChiKey: NQMFMRSQERHEJO-AWEZNQCLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (S)-(-)- α-甲基苄胺 、 ethyl 2-(1-naphthylamino)-2-oxoacetate 生成 N-Naphthalen-1-yl-N'-((S)-1-phenyl-ethyl)-oxalamide
  参考文献：
  名称：

  A New Class of Near-Infrared Electrochromic Oxamide-Based Dinuclear Ruthenium Complexes

  摘要：

  We report the synthesis of a new class of symmetric and unsymmetric oxamide-based dinuclear ruthenium complexes. These complexes were characterized by NMR, ESI-MS, and electrochemical methods. Spectroelectrochernical analysis of the complexes showed broad absorptions in the NIR region for the mixed-valence state of the complexes. The introduction of a chiral group into the bridging ligand produced an optically active complex that was studied using circular dichroism.

  DOI：

  10.1021/ol048021b