(3-{3-[3-(Phenyl-pyren-1-yl-amino)-benzyloxy]-benzyloxy}-phenyl)-methanol | 903562-01-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: (3-{3-[3-(Phenyl-pyren-1-yl-amino)-benzyloxy]-benzyloxy}-phenyl)-methanol
• 英文别名: [3-[[3-[[3-(N-pyren-1-ylanilino)phenyl]methoxy]phenyl]methoxy]phenyl]methanol
• CAS: 903562-01-6
• 化学式: C₄₃H₃₃NO₃
• 分子量: 611.74
• InChiKey: SUCNKUWQNVBTRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  47
• 可旋转键数：
  10
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  41.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (3-{3-[3-(Phenyl-pyren-1-yl-amino)-benzyloxy]-benzyloxy}-phenyl)-methanol 、 4,7-bis(5-(3-hydroxyphenyl)thiophen-2-yl)benzo[c][1,2,5]thiadiazole 在 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以72%的产率得到N-phenyl-N-[3-[[3-[[3-[[3-[5-[4-[5-[3-[[3-[[3-[[3-(N-pyren-1-ylanilino)phenyl]methoxy]phenyl]methoxy]phenyl]methoxy]phenyl]thiophen-2-yl]-2,1,3-benzothiadiazol-7-yl]thiophen-2-yl]phenoxy]methyl]phenoxy]methyl]phenoxy]methyl]phenyl]pyren-1-amine
  参考文献：
  名称：

  Dendrimer Analogues of Linear Molecules to Evaluate Energy and Charge-Transfer Properties

  摘要：

  We have designed and synthesized difunctionalized dendrimers containing two donors in the periphery and an acceptor at the core to serve as scaffolds for comparison with linear analogues to investigate the advantage of dendritic scaffolds for energy and charge transfer. Comparison of these dendrimers with the fully decorated dendrimers provides information on the advantage of chromophore density in energy/charge transfer from periphery to the core.

  DOI：

  10.1021/ol0608956
• 作为产物：
  描述：

  3-甲氧基甲氧基苄醇 在 sodium tetrahydroborate 、 对甲苯磺酸 、 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 、 甲醇 、 乙醇 为溶剂， 反应 3.0h， 生成 (3-{3-[3-(Phenyl-pyren-1-yl-amino)-benzyloxy]-benzyloxy}-phenyl)-methanol
  参考文献：
  名称：

  Dendrimer Analogues of Linear Molecules to Evaluate Energy and Charge-Transfer Properties

  摘要：

  We have designed and synthesized difunctionalized dendrimers containing two donors in the periphery and an acceptor at the core to serve as scaffolds for comparison with linear analogues to investigate the advantage of dendritic scaffolds for energy and charge transfer. Comparison of these dendrimers with the fully decorated dendrimers provides information on the advantage of chromophore density in energy/charge transfer from periphery to the core.

  DOI：

  10.1021/ol0608956

文献信息

• Dendrimer Analogues of Linear Molecules to Evaluate Energy and Charge-Transfer Properties
  作者：Arpornrat Nantalaksakul、Raghunath Reddy Dasari、Tai-Sang Ahn、Rabih Al-Kaysi、Christopher J. Bardeen、S. Thayumanavan

  DOI：10.1021/ol0608956

  日期：2006.7.1

  We have designed and synthesized difunctionalized dendrimers containing two donors in the periphery and an acceptor at the core to serve as scaffolds for comparison with linear analogues to investigate the advantage of dendritic scaffolds for energy and charge transfer. Comparison of these dendrimers with the fully decorated dendrimers provides information on the advantage of chromophore density in energy/charge transfer from periphery to the core.