β-chloroethyl-1 3,4-dimethyl phosphole | 102967-72-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: β-chloroethyl-1 3,4-dimethyl phosphole
• 英文别名: 1-(2-Chloroethyl)-3,4-dimethylphosphole
• CAS: 102967-72-6
• 化学式: C₈H₁₂ClP
• 分子量: 174.61
• InChiKey: TUPAPGGBLKVYSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  N-苯基马来酰亚胺 、 β-chloroethyl-1 3,4-dimethyl phosphole 生成
  参考文献：
  名称：

  7-Phosphanorbornenium Borohydrides: A Powerful Route to Functional Secondary Phosphine−Borane Complexes

  摘要：

  The reaction of phosphanorbornenium triflates with sodium borohydride gives the secondary phosphine borane complexes by reductive cleavage of the two P C bonds of the bridge. This route is compatible with functionalities such as Cl, CN, CO(2)Et, and Th.

  DOI：

  10.1021/om100053d
• 作为产物：
  描述：

  1,2-二氯乙烷 、 1-苯基-3,4-二甲基膦杂环戊二烯) 生成 β-chloroethyl-1 3,4-dimethyl phosphole
  参考文献：
  名称：

  Conversion directe des phospholes en dihydro-6,7 phosphepines dans la sphere de coordination du tungstene

  摘要：

  DOI：

  10.1016/s0040-4039(00)98664-7

文献信息

• [EN] PHOSPHIRENE DERIVED CATALYSTS<br/>[FR] CATALYSEURS DERIVES DE PHOSPHIRENE
  申请人：JOHNSON MATTHEY PLC

  公开号：WO2002102509A1

  公开（公告）日：2002-12-27

  Catalysts are described comprising the reaction product of a metal compound and a compound containing a phosphirene moiety of general formula (I) in which R?1, R2 and R3¿ represent independently hydrogen, alkyl (having between 1 and 24 carbon atoms), substituted alkyl or cycloalkyl, heterocycle or substituted heterocycle, aryl or substituted aryl, ferrocenyl or ruthenocyl. Catalysts based on e.g. palladium and such phosphirene compounds may be used for example in hydrogenation, Heck or amination reactions.
• Conversion directe des phospholes en dihydro-6,7 phosphepines dans la sphere de coordination du tungstene
  作者：Bernard Deschamps、François Mathey

  DOI：10.1016/s0040-4039(00)98664-7

  日期：1985.1
• 7-Phosphanorbornenium Borohydrides: A Powerful Route to Functional Secondary Phosphine−Borane Complexes
  作者：Rongqiang Tian、François Mathey

  DOI：10.1021/om100053d

  日期：2010.4.26

  The reaction of phosphanorbornenium triflates with sodium borohydride gives the secondary phosphine borane complexes by reductive cleavage of the two P C bonds of the bridge. This route is compatible with functionalities such as Cl, CN, CO(2)Et, and Th.