N,N'-二辛基己烷二酰胺 | 37118-48-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: N,N'-二辛基己烷二酰胺
• 英文名称: N,N'-dioctyl-hexanediamide
• 英文别名: hexane-1,6-dioic acid bis(octylamide)；N,N'-dioctylhexanediamide
• CAS: 37118-48-2
• 化学式: C₂₂H₄₄N₂O₂
• 分子量: 368.604
• InChiKey: ZGZLVCQADFTQMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  26
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  己二酸 在 氯化亚砜 、 三乙胺 、 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 N,N'-二辛基己烷二酰胺
  参考文献：
  名称：

  Self-Assembly, Binding, and Dynamic Properties of Heterodimeric Porphyrin Macrocycles

  摘要：

  [GRAPHICS]A series of heterodimeric tetralactam macrocycles have been self-assembled using two kinetically labile zinc porphyrin-pyridine interactions. The stability constants have been determined by UVvis titrations in CHCl(3). The stability constants depend on the degree of preorganization of the linker units connecting the interacting groups. The ability of the self-assembled macrocycles to bind a terephthalamide guest was also investigated. One of the macrocycles was used for the construction of a [2]rotaxane. The dynamic properties of this system provide insight into the exchange mechanisms that operate in complex noncovalent assemblies.

  DOI：

  10.1021/jo0505369

文献信息

• Self-assembly of [2]Rotaxane Exploiting Reversible Pt(II)- Pyridine Coordinate Bonds
  作者：Pablo Ballester、Magdalena Capó、Antoni Costa、Pere Deyà、Antoni Frontera、Rosa Gomila

  DOI：10.3390/90500278

  日期：——

  A dinuclear self-assembled cationic macrocycle based on Pt(II)-N(pyridine) coordinative bonds and having competitive triflate anions, as metal counterions, is used in the construction of [2]rotaxane and [2]pseudorotaxane architectures assisted by hydrogen bonding. The kinetic lability of the Pt(II)-N(pyridine) coordinative bond controls the dynamics of the [2]rotaxane.

  一个基于铂(II)-N(吡啶)配位键的二核自组装阳离子大环，具有与金属对离子竞争的三氟甲磺酸阴离子，用于构建由氢键辅助的[2]旋转链和[2]伪旋转链结构。铂(II)-N(吡啶)配位键的动力学活性控制着[2]旋转链的动态性。
• US5346878A
  申请人：——

  公开号：US5346878A

  公开（公告）日：1994-09-13
• US5476957A
  申请人：——

  公开号：US5476957A

  公开（公告）日：1995-12-19
• Self-Assembly, Binding, and Dynamic Properties of Heterodimeric Porphyrin Macrocycles
  作者：Pablo Ballester、Antoni Costa、Pere M. Deyà、Antonio Frontera、Rosa M. Gomila、Ana I. Oliva、Jeremy K. M. Sanders、Christopher A. Hunter

  DOI：10.1021/jo0505369

  日期：2005.8.1

  [GRAPHICS]A series of heterodimeric tetralactam macrocycles have been self-assembled using two kinetically labile zinc porphyrin-pyridine interactions. The stability constants have been determined by UVvis titrations in CHCl(3). The stability constants depend on the degree of preorganization of the linker units connecting the interacting groups. The ability of the self-assembled macrocycles to bind a terephthalamide guest was also investigated. One of the macrocycles was used for the construction of a [2]rotaxane. The dynamic properties of this system provide insight into the exchange mechanisms that operate in complex noncovalent assemblies.